VAMAS Surface Chemical Analysis Standard Data Transfer Format 1988 May 4 Not Specified Not Specified Not Specified Not Specified 7 Casa Info Follows 0 SourceAnalyserAngle: Not Specified CasaRowLabel:PNB80 CasaRowLabel:PNB300 CasaRowLabel:PNB500 CasaRowLabel:PNB700 MAP REGULAR 6 0 0 0 1 Data Set d 0 0 0 0 24 wide/1 PNB80 2015 10 14 9 21 56 0 10 Casa Info Follows 1 Calib M = 280.821 A = 284.6 BE ADD 0 0 0 pnb.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 160 Acqn. Time(s): 603 Sweeps: 5 Anode:Mono(Al (Mono))(156 W) Step(meV): 1000.0 Dwell Time(ms): 100 Charge Neutraliser :On Acquired On :15/10/14 09:21:56 XPS 29 8 0 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 160 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Wide None -1 Kinetic Energy eV 286.69 1 2 Intensity d Transmission d pulse counting 0.1 5 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 2412 1 1577 4.41569 8.42235 364 8.42235 337 8.38839 367 8.35442 343 8.32045 328 8.28649 326 8.25252 334 8.21856 336 8.18459 339 8.15063 342 8.11666 310 8.0827 325 8.04873 343 8.01476 320 7.9808 322 7.94683 306 7.91287 346 7.8789 315 7.84494 339 7.81097 352 7.77701 335 7.74304 318 7.70907 363 7.67511 354 7.64114 340 7.60718 314 7.57321 327 7.53925 345 7.50528 367 7.47131 361 7.43735 321 7.40338 373 7.36942 352 7.33545 337 7.30149 337 7.26752 322 7.23356 334 7.19959 337 7.16562 338 7.13166 345 7.09769 363 7.06373 345 7.02976 350 7.00512 343 6.99202 318 6.97893 345 6.96583 340 6.95273 359 6.93963 350 6.92653 321 6.91343 330 6.90033 346 6.88723 360 6.87414 365 6.86104 340 6.84794 316 6.83484 323 6.82174 325 6.80864 380 6.79554 335 6.78244 357 6.76935 352 6.75625 348 6.74315 357 6.73005 327 6.71695 311 6.70385 346 6.69075 359 6.67765 377 6.66456 347 6.65146 335 6.63836 313 6.62526 336 6.61216 337 6.59906 360 6.58596 353 6.57286 328 6.55976 371 6.54667 322 6.53357 370 6.52047 335 6.50737 325 6.49427 337 6.48117 333 6.46807 340 6.45497 341 6.44188 342 6.42878 353 6.41568 344 6.40258 393 6.38948 380 6.37638 359 6.36328 353 6.35018 343 6.33709 351 6.32399 362 6.31089 353 6.29779 360 6.28469 357 6.27159 349 6.25849 346 6.24539 387 6.2323 385 6.2192 368 6.2061 361 6.193 346 6.1799 365 6.1668 379 6.1537 336 6.1406 378 6.1275 349 6.11441 354 6.10131 361 6.08821 365 6.07511 363 6.06201 357 6.04891 344 6.03581 347 6.02271 373 6.00962 335 5.99652 374 5.98342 349 5.97032 347 5.95722 360 5.94412 362 5.93102 391 5.91792 367 5.90483 367 5.89173 356 5.87863 384 5.86553 401 5.85243 387 5.83933 407 5.82623 384 5.81313 362 5.80004 335 5.78694 383 5.77384 370 5.76074 361 5.74764 377 5.73454 345 5.72144 388 5.70834 412 5.69524 397 5.68215 348 5.66905 345 5.65595 399 5.64285 387 5.62975 396 5.61665 398 5.60355 373 5.59045 399 5.57736 405 5.56426 403 5.55116 393 5.53806 416 5.52496 390 5.51186 387 5.49876 424 5.48566 429 5.47257 401 5.45947 375 5.44637 388 5.43327 379 5.42017 394 5.40707 364 5.39397 406 5.38087 412 5.36778 391 5.35468 363 5.34158 381 5.33457 385 5.33071 371 5.32684 389 5.32297 424 5.31911 413 5.31524 394 5.31137 418 5.30751 397 5.30364 380 5.29978 418 5.29591 409 5.29204 404 5.28818 415 5.28431 382 5.28044 419 5.27658 396 5.27271 430 5.26885 424 5.26498 383 5.26111 417 5.25725 429 5.25338 431 5.24951 430 5.24565 422 5.24178 418 5.23792 405 5.23405 431 5.23018 452 5.22632 435 5.22245 477 5.21858 426 5.21472 429 5.21085 433 5.20699 438 5.20312 426 5.19925 455 5.19539 487 5.19152 448 5.18765 448 5.18379 431 5.17992 439 5.17606 448 5.17219 460 5.16832 452 5.16446 421 5.16059 417 5.15672 423 5.15286 407 5.14899 400 5.14513 395 5.14126 410 5.13739 408 5.13353 420 5.12966 412 5.12579 472 5.12193 473 5.11806 522 5.1142 544 5.11033 557 5.10646 536 5.1026 481 5.09873 445 5.09486 434 5.091 417 5.08713 406 5.08327 363 5.0794 370 5.07553 388 5.07167 332 5.0678 361 5.06393 317 5.06007 326 5.0562 336 5.05234 332 5.04847 330 5.0446 323 5.04074 318 5.03687 356 5.033 300 5.02914 347 5.02527 346 5.02141 328 5.01754 333 5.01367 321 5.00981 335 5.00594 318 5.00207 323 4.99821 345 4.99434 354 4.99048 326 4.98661 325 4.98274 318 4.97888 348 4.97501 353 4.97114 338 4.96728 340 4.96341 349 4.95955 337 4.95568 341 4.95181 355 4.94795 348 4.94408 370 4.94021 339 4.93635 362 4.93248 338 4.92862 354 4.92475 342 4.92088 324 4.91702 342 4.91315 333 4.90928 331 4.90542 355 4.90155 335 4.89769 342 4.89382 356 4.88995 337 4.88609 369 4.88222 328 4.87835 346 4.87449 358 4.87062 338 4.86676 339 4.86289 333 4.85902 342 4.85516 341 4.85129 377 4.84742 344 4.84356 338 4.83969 339 4.83582 364 4.83196 355 4.82809 328 4.82423 336 4.82036 359 4.81649 369 4.81263 341 4.80876 326 4.80489 354 4.80103 355 4.79716 399 4.7933 407 4.78943 375 4.78556 367 4.7817 365 4.77783 338 4.77396 375 4.7701 366 4.76623 361 4.76237 374 4.7585 380 4.75463 380 4.75077 366 4.7469 368 4.74303 391 4.73917 369 4.7353 367 4.73144 350 4.72757 376 4.7237 355 4.71984 336 4.71597 362 4.7121 379 4.70824 383 4.70437 364 4.70051 382 4.69664 358 4.69277 363 4.68891 372 4.68504 357 4.68117 359 4.67731 417 4.67344 413 4.66958 372 4.66571 351 4.66184 378 4.65798 372 4.65411 378 4.65024 399 4.64638 364 4.64251 345 4.63865 356 4.63478 353 4.63091 352 4.62705 363 4.62318 346 4.61931 391 4.61545 392 4.61158 369 4.60772 383 4.60385 393 4.59998 408 4.59612 388 4.59225 389 4.58838 356 4.58452 394 4.58065 418 4.57679 390 4.57292 397 4.56905 377 4.56519 351 4.56132 400 4.55745 375 4.55359 384 4.54972 379 4.54586 398 4.54199 375 4.53812 388 4.53426 383 4.53039 397 4.52906 401 4.52854 373 4.52803 390 4.52752 377 4.52701 395 4.52649 423 4.52598 393 4.52547 370 4.52495 402 4.52444 404 4.52393 395 4.52341 370 4.5229 400 4.52239 415 4.52188 432 4.52136 408 4.52085 420 4.52034 392 4.51982 411 4.51931 403 4.5188 423 4.51828 434 4.51777 389 4.51726 400 4.51675 431 4.51623 475 4.51572 409 4.51521 405 4.51469 412 4.51418 402 4.51367 427 4.51315 430 4.51264 426 4.51213 444 4.51162 433 4.5111 412 4.51059 415 4.51008 413 4.50956 402 4.50905 420 4.50854 418 4.50803 401 4.50751 396 4.507 411 4.50649 440 4.50597 466 4.50546 427 4.50495 417 4.50443 401 4.50392 420 4.50341 441 4.50289 421 4.50238 454 4.50187 434 4.50136 437 4.50084 409 4.50033 408 4.49982 450 4.4993 453 4.49879 413 4.49828 438 4.49777 454 4.49725 403 4.49674 408 4.49623 415 4.49571 465 4.4952 429 4.49469 436 4.49417 468 4.49366 431 4.49315 495 4.49264 496 4.49212 451 4.49161 420 4.4911 427 4.49058 402 4.49007 464 4.48956 460 4.48904 468 4.48853 476 4.48802 445 4.48751 489 4.48699 439 4.48648 468 4.48597 482 4.48545 435 4.48494 405 4.48443 473 4.48391 459 4.4834 452 4.48289 491 4.48238 453 4.48186 460 4.48135 478 4.48084 463 4.48032 471 4.47981 471 4.4793 482 4.47878 437 4.47827 475 4.47776 499 4.47725 458 4.47673 468 4.47622 508 4.47571 458 4.47519 507 4.47468 460 4.47417 443 4.47365 450 4.47314 446 4.47263 473 4.47212 450 4.4716 491 4.47109 476 4.47058 486 4.47006 473 4.46955 466 4.46904 483 4.46852 478 4.46801 467 4.4675 446 4.46699 467 4.46647 539 4.46596 486 4.46545 501 4.46493 478 4.46442 457 4.46391 457 4.46339 457 4.46288 492 4.46237 445 4.46186 476 4.46134 445 4.46083 474 4.46032 477 4.4598 467 4.45929 478 4.45878 518 4.45826 517 4.45775 501 4.45724 499 4.45673 498 4.45621 483 4.4557 465 4.45519 527 4.45467 524 4.45416 455 4.45365 493 4.45313 484 4.45262 512 4.45211 498 4.4516 489 4.45108 495 4.45057 504 4.45006 502 4.44954 534 4.44903 520 4.44852 510 4.448 548 4.44749 506 4.44698 503 4.44647 513 4.44595 521 4.44544 487 4.44493 504 4.44441 521 4.4439 505 4.44339 525 4.44287 506 4.44236 513 4.44185 523 4.44134 520 4.44082 562 4.44031 529 4.4398 508 4.43928 543 4.43877 534 4.43826 496 4.43775 504 4.43723 528 4.43672 534 4.43621 520 4.43569 568 4.43518 532 4.43467 594 4.43415 530 4.43364 512 4.43313 518 4.43262 510 4.4321 549 4.43159 547 4.43108 545 4.43056 507 4.43005 534 4.42954 532 4.42902 548 4.42851 565 4.428 528 4.42748 559 4.42697 581 4.42646 556 4.42595 563 4.42543 556 4.42492 529 4.42441 495 4.42389 574 4.42338 560 4.42287 554 4.42236 536 4.42184 556 4.42133 570 4.42082 497 4.4203 527 4.41979 568 4.41928 617 4.41876 537 4.41825 547 4.41774 553 4.41723 582 4.41671 599 4.4162 552 4.41569 573 4.41652 618 4.41746 559 4.41841 568 4.41936 552 4.4203 613 4.42125 554 4.4222 566 4.42315 588 4.42409 595 4.42504 556 4.42599 593 4.42694 585 4.42788 606 4.42883 596 4.42978 580 4.43073 566 4.43167 565 4.43262 593 4.43357 545 4.43451 606 4.43546 580 4.43641 571 4.43736 575 4.4383 605 4.43925 608 4.4402 597 4.44115 614 4.44209 590 4.44304 576 4.44399 605 4.44494 591 4.44588 598 4.44683 594 4.44778 601 4.44873 586 4.44967 578 4.45062 591 4.45157 595 4.45251 612 4.45346 566 4.45441 631 4.45536 617 4.4563 600 4.45725 647 4.4582 609 4.45915 614 4.46009 605 4.46104 611 4.46199 629 4.46294 609 4.46388 592 4.46483 587 4.46578 588 4.46672 625 4.46767 619 4.46862 637 4.46957 632 4.47051 635 4.47146 639 4.47241 620 4.47336 575 4.4743 578 4.47525 552 4.4762 543 4.47715 532 4.47809 490 4.47904 536 4.47999 514 4.48094 589 4.48188 791 4.48283 1135 4.48378 1577 4.48472 1484 4.48567 923 4.48662 567 4.48757 478 4.48851 458 4.48946 473 4.49041 447 4.49136 476 4.4923 462 4.49325 485 4.4942 476 4.49515 484 4.49609 441 4.49704 441 4.49799 484 4.49893 469 4.49988 463 4.50083 476 4.50178 475 4.50272 477 4.50367 463 4.50462 478 4.50557 473 4.50651 491 4.50746 474 4.50841 484 4.50936 508 4.5103 503 4.51125 487 4.5122 483 4.51314 500 4.51409 504 4.51504 494 4.51599 447 4.51693 470 4.51788 476 4.51883 521 4.51978 490 4.52072 548 4.52167 478 4.52262 469 4.52357 526 4.52451 505 4.52546 500 4.52641 489 4.52736 488 4.5283 509 4.52925 489 4.5302 491 4.53114 492 4.53209 475 4.53304 511 4.53399 515 4.53493 520 4.53588 462 4.53683 515 4.53778 506 4.53872 546 4.53967 562 4.54062 554 4.54157 578 4.54251 578 4.54346 546 4.54441 521 4.54535 498 4.5463 490 4.54725 491 4.5482 472 4.54914 492 4.55009 526 4.55104 510 4.55199 479 4.55293 474 4.55388 463 4.55483 482 4.55578 487 4.55764 434 4.5599 451 4.56217 489 4.56443 454 4.56669 463 4.56896 511 4.57122 512 4.57349 473 4.57575 489 4.57801 466 4.58028 490 4.58254 483 4.58481 461 4.58707 467 4.58933 491 4.5916 505 4.59386 512 4.59613 508 4.59839 492 4.60065 513 4.60292 485 4.60518 498 4.60745 491 4.60971 470 4.61197 494 4.61424 514 4.6165 489 4.61877 497 4.62103 528 4.62329 527 4.62556 476 4.62782 490 4.63009 505 4.63235 494 4.63461 484 4.63688 504 4.63914 503 4.64141 516 4.64367 529 4.64593 508 4.6482 500 4.65046 517 4.65273 515 4.65499 516 4.65725 538 4.65952 542 4.66178 524 4.66405 500 4.66631 496 4.66857 501 4.67084 513 4.6731 524 4.67537 516 4.67763 512 4.67989 540 4.68216 526 4.68442 550 4.68669 507 4.68895 554 4.69121 564 4.69348 606 4.69574 519 4.69801 481 4.70027 519 4.70253 499 4.7048 512 4.70706 547 4.70933 549 4.71159 517 4.71385 527 4.71612 518 4.71838 621 4.72065 759 4.72291 863 4.72517 781 4.72744 645 4.7297 570 4.73197 525 4.73423 460 4.73649 444 4.73876 455 4.74102 469 4.74329 442 4.74555 428 4.74781 443 4.75008 507 4.75234 590 4.75461 831 4.75687 1013 4.75913 961 4.7614 764 4.76366 527 4.76593 407 4.76819 353 4.77045 371 4.77272 367 4.77498 334 4.77725 329 4.77951 353 4.78177 325 4.78404 304 4.7863 325 4.78857 313 4.79083 318 4.79309 309 4.79536 330 4.79762 319 4.79989 337 4.80215 327 4.80441 338 4.80668 350 4.80894 306 4.81121 327 4.81347 333 4.81573 330 4.818 333 4.82026 328 4.82253 341 4.82479 352 4.82705 322 4.82932 308 4.83158 346 4.83385 330 4.83611 341 4.83837 348 4.84064 318 4.8429 329 4.84517 332 4.84743 314 4.84969 316 4.85196 330 4.85422 358 4.85648 324 4.85875 364 4.86101 359 4.86328 336 4.86554 375 4.86781 340 4.87007 356 4.87233 338 4.8746 310 4.87686 351 4.87913 324 4.88139 345 4.88365 342 4.88592 335 4.88818 349 4.89044 361 4.89271 335 4.89497 369 4.89724 325 4.8995 330 4.90176 339 4.90403 350 4.90629 361 4.90856 340 4.91082 351 4.91308 326 4.91535 329 4.91761 348 4.91988 323 4.92214 363 4.9244 348 4.92667 317 4.92893 369 4.9312 363 4.93346 376 4.93572 426 4.93799 539 4.94025 559 4.94252 475 4.94478 388 4.94704 358 4.94931 329 4.95157 331 4.95384 333 4.9561 319 4.95836 316 4.96063 307 4.96289 339 4.96516 332 4.96742 323 4.96968 349 4.97195 333 4.97421 354 4.97648 354 4.97874 371 4.981 349 4.98327 350 4.98553 344 4.9878 331 4.99006 359 4.99232 337 4.99459 335 4.99685 345 4.99912 323 5.00138 358 5.00364 353 5.00591 375 5.00817 336 5.01044 378 5.01342 354 5.01665 354 5.01988 345 5.02311 346 5.02633 343 5.02956 347 5.03279 341 5.03601 344 5.03924 336 5.04247 325 5.0457 331 5.04892 341 5.05215 349 5.05538 332 5.05861 359 5.06183 365 5.06506 375 5.06829 366 5.07152 377 5.07474 384 5.07797 371 5.0812 360 5.08442 382 5.08765 329 5.09088 357 5.09411 377 5.09733 383 5.10056 380 5.10379 431 5.10702 440 5.11024 408 5.11347 418 5.1167 346 5.11993 328 5.12315 303 5.12638 294 5.12961 321 5.13283 288 5.13606 290 5.13929 255 5.14252 257 5.14574 401 5.14897 838 5.1522 1047 5.15543 1029 5.15865 1372 5.16188 1386 5.16511 707 5.16834 223 5.17156 102 5.17479 87 5.17802 88 5.18124 75 5.18447 98 5.1877 99 5.19093 91 5.19415 81 5.19738 70 5.20061 60 5.20384 72 5.20706 81 5.21029 75 5.21352 84 5.21675 81 5.21997 87 5.2232 82 5.22643 90 5.22965 76 5.23288 85 5.23611 95 5.23934 96 5.24256 98 5.24579 75 5.24902 79 5.25225 91 5.25547 73 5.2587 79 5.26193 81 5.26516 73 5.26838 80 5.27161 65 5.27484 69 5.27806 77 5.28129 73 5.28452 83 5.28775 66 5.29097 75 5.2942 81 5.29743 88 5.30066 81 5.30388 70 5.30711 88 5.31034 82 5.31381 79 5.31803 75 5.32226 77 5.32648 64 5.33071 84 5.33493 92 5.33916 88 5.34338 84 5.34761 84 5.35183 83 5.35606 81 5.36028 82 5.36451 79 5.36873 80 5.37296 70 5.37718 60 5.38141 88 5.38564 89 5.38986 94 5.39409 85 5.39831 82 5.40254 71 5.40676 82 5.41099 73 5.41521 94 5.41944 93 5.42366 87 5.42789 86 5.43211 89 5.43634 77 5.44056 95 5.44479 99 5.44902 86 5.45324 85 5.45747 79 5.46169 82 5.46592 101 5.47014 94 5.47437 79 5.47859 88 5.48282 78 5.48704 87 5.49127 82 5.49549 76 5.49972 73 5.50394 94 5.50817 87 5.5124 85 5.51662 77 5.52085 92 5.52507 76 5.5293 73 5.53352 63 5.53775 79 5.54197 93 5.5462 97 5.55042 106 5.55465 94 5.55887 94 5.5631 98 5.56732 84 5.57155 89 5.57578 90 5.58 97 5.58423 100 5.58845 91 5.59268 83 5.5969 107 5.60113 98 5.60535 98 5.60958 98 5.6138 86 5.61803 94 5.62225 89 5.62648 97 5.6307 103 5.63493 72 5.63916 111 5.64338 112 5.64761 107 5.65183 103 5.65606 88 5.66028 85 5.66451 96 5.66873 106 5.67296 96 5.67718 88 5.68141 95 5.68563 99 5.68986 99 5.69408 107 5.69831 98 5.70254 96 5.70676 86 5.71099 93 5.71521 97 5.71944 82 5.72366 130 5.72789 121 5.73211 138 5.73634 151 5.74056 124 5.74479 98 5.74901 91 5.75324 87 5.75746 115 5.76169 94 5.76591 81 5.77014 76 5.77437 92 5.77859 101 5.78282 81 5.78704 86 5.79127 86 5.79549 85 5.79972 73 5.80394 81 5.80817 103 5.81239 82 5.81662 79 5.82084 88 5.82507 109 5.8293 172 5.83352 246 5.83775 254 5.84197 222 5.8462 154 5.85042 82 5.85465 54 5.85887 43 5.8631 45 5.86732 39 5.87155 44 5.87577 39 5.87603 40 5.87603 57 5.87603 70 5.87603 83 5.87603 113 5.87603 76 5.87603 55 5.87603 45 5.87603 29 5.87603 17 5.87603 21 5.87603 16 5.87603 14 5.87603 19 5.87603 8 5.87603 14 5.87603 11 5.87603 33 5.87603 57 5.87603 59 5.87603 64 5.87603 49 5.87603 24 5.87603 21 5.87603 6 5.87603 1 5.87603 1 5.87603 1 5.87603 O 1s/2 PNB80 2015 10 14 9 41 26 0 13 Casa Info Follows 1 Calib M = 280.821 A = 284.6 BE ADD 0 1 CASA region (*O 1s*) (*Shirley*) 949.25561 961.07525 0.78 2 0 0 299 542 275 9.3 (*O 1s*) 15.9994 0 2 CASA comp (*O 1s*) (*GL(30)*) Area 2932.073 0.001 10000000 -1 1 MFWHM 1.7218448 0.38 9.5 -1 1 Position 956.1925 942.911 962.911 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) CASA comp (*O 1s*) (*GL(30)*) Area 392.49507 0.001 10000000 -1 1 MFWHM 1.5766369 0.38 9.5 -1 1 Position 954.34047 942.911 962.911 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) pnb.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 666 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 332 Charge Neutraliser :On Acquired On :15/10/14 09:41:26 XPS 55 6 0 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 O 1s -1 Kinetic Energy eV 946.69 0.1 2 Intensity d Transmission d pulse counting 0.3315 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 1367 6767 1.31473 1.31659 1973 1.31659 1982 1.31658 2001 1.31657 2009 1.31656 1943 1.31655 1879 1.31654 1961 1.31653 1886 1.31652 1941 1.31651 1857 1.3165 1874 1.3165 1949 1.31649 1852 1.31648 1942 1.31647 1872 1.31646 1871 1.31645 1872 1.31644 1904 1.31643 1901 1.31642 1846 1.31641 1848 1.3164 1800 1.31639 1852 1.31638 1803 1.31637 1805 1.31637 1784 1.31636 1777 1.31635 1830 1.31634 1867 1.31633 1777 1.31632 1792 1.31631 1714 1.3163 1726 1.31629 1801 1.31628 1757 1.31627 1706 1.31626 1726 1.31625 1749 1.31624 1706 1.31623 1713 1.31623 1793 1.31622 1740 1.31621 1697 1.3162 1733 1.31619 1736 1.31618 1746 1.31617 1762 1.31616 1774 1.31615 1746 1.31614 1735 1.31613 1751 1.31612 1713 1.31611 1685 1.3161 1676 1.3161 1645 1.31609 1683 1.31608 1704 1.31607 1741 1.31606 1696 1.31605 1687 1.31604 1728 1.31603 1704 1.31602 1697 1.31601 1745 1.316 1681 1.31599 1696 1.31598 1682 1.31597 1652 1.31597 1712 1.31596 1711 1.31595 1704 1.31594 1715 1.31593 1597 1.31592 1642 1.31591 1671 1.3159 1694 1.31589 1682 1.31588 1635 1.31587 1703 1.31586 1724 1.31585 1733 1.31584 1660 1.31584 1644 1.31583 1685 1.31582 1653 1.31581 1610 1.3158 1645 1.31579 1683 1.31578 1660 1.31577 1649 1.31576 1663 1.31575 1590 1.31574 1614 1.31573 1640 1.31572 1729 1.31571 1585 1.3157 1663 1.3157 1706 1.31569 1759 1.31568 1753 1.31567 1693 1.31566 1831 1.31565 1884 1.31564 1919 1.31563 1963 1.31562 2063 1.31561 2071 1.3156 2180 1.31559 2240 1.31558 2333 1.31557 2361 1.31557 2511 1.31556 2496 1.31555 2600 1.31554 2708 1.31553 2801 1.31552 2779 1.31551 2954 1.3155 3104 1.31549 3296 1.31548 3453 1.31547 3607 1.31546 3800 1.31545 4071 1.31544 4500 1.31544 4700 1.31543 5145 1.31542 5516 1.31541 5912 1.3154 6184 1.31539 6504 1.31538 6720 1.31537 6703 1.31536 6767 1.31535 6615 1.31534 6636 1.31533 6257 1.31532 5791 1.31531 5462 1.31531 5084 1.3153 4803 1.31529 4294 1.31528 3817 1.31527 3557 1.31526 3078 1.31525 2705 1.31524 2503 1.31523 2294 1.31522 2137 1.31521 2021 1.3152 1855 1.31519 1774 1.31518 1674 1.31517 1631 1.31517 1564 1.31516 1563 1.31515 1534 1.31514 1522 1.31513 1519 1.31512 1450 1.31511 1504 1.3151 1464 1.31509 1542 1.31508 1452 1.31507 1391 1.31506 1447 1.31505 1450 1.31504 1451 1.31504 1457 1.31503 1401 1.31502 1412 1.31501 1391 1.315 1429 1.31499 1448 1.31498 1492 1.31497 1443 1.31496 1476 1.31495 1415 1.31494 1460 1.31493 1377 1.31492 1367 1.31491 1505 1.31491 1440 1.3149 1447 1.31489 1570 1.31488 1423 1.31487 1440 1.31486 1489 1.31485 1467 1.31484 1461 1.31483 1409 1.31482 1497 1.31481 1489 1.3148 1378 1.31479 1422 1.31478 1451 1.31478 1384 1.31477 1471 1.31476 1407 1.31475 1455 1.31474 1481 1.31473 Nb 3p/3 PNB80 2015 10 14 9 41 26 0 15 Casa Info Follows 1 Calib M = 280.821 A = 284.6 BE ADD 0 1 CASA region (*Nb 3p*) (*Shirley*) 1098.9174 1128.605 2.63 2 0 0 299 542 275 9.3 (*Nb 3p*) 92.9064 0 4 CASA comp (*Nb 3p*) (*GL(30)*) Area 2145.5768 0.001 10000000 -1 1 MFWHM 2.5474967 0.54 13.5 -1 1 Position 1121.0861 1090.911 1134.911 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 1278.1063 0.001 10000000 -1 1 MFWHM 2.5940518 0.54 13.5 -1 1 Position 1105.6133 1090.911 1134.911 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 356.63637 0.001 10000000 -1 1 MFWHM 3.8078623 0.57788815 14.447204 -1 1 Position 1123.4149 1090.911 1134.911 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 240.38063 0.001 10000000 -1 1 MFWHM 3.1979853 0.62247009 15.561752 -1 1 Position 1108.1963 1090.911 1134.911 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) pnb.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 2871 Sweeps: 50 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 130 Charge Neutraliser :On Acquired On :15/10/14 09:41:26 XPS 55 6 0 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3p -1 Kinetic Energy eV 1094.69 0.1 2 Intensity d Transmission d pulse counting 0.1302 50 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 882 1930 7877 1.26578 1.28386 3449 1.28386 3504 1.28381 3410 1.28377 3395 1.28373 3421 1.28369 3523 1.28365 3520 1.28361 3437 1.28357 3356 1.28353 3384 1.28349 3379 1.28344 3420 1.2834 3346 1.28336 3492 1.28332 3429 1.28328 3513 1.28324 3525 1.2832 3412 1.28316 3325 1.28312 3423 1.28307 3496 1.28303 3371 1.28299 3430 1.28295 3384 1.28291 3307 1.28287 3363 1.28283 3383 1.28279 3308 1.28275 3367 1.2827 3396 1.28266 3376 1.28262 3324 1.28258 3425 1.28254 3422 1.2825 3311 1.28246 3317 1.28242 3239 1.28238 3436 1.28234 3212 1.28229 3423 1.28225 3321 1.28221 3207 1.28217 3313 1.28213 3393 1.28209 3268 1.28205 3396 1.28201 3241 1.28197 3254 1.28192 3332 1.28188 3403 1.28184 3402 1.2818 3273 1.28176 3370 1.28172 3280 1.28168 3285 1.28164 3331 1.2816 3334 1.28155 3321 1.28151 3263 1.28147 3311 1.28143 3300 1.28139 3284 1.28135 3285 1.28131 3269 1.28127 3236 1.28123 3384 1.28118 3143 1.28114 3415 1.2811 3273 1.28106 3483 1.28102 3379 1.28098 3411 1.28094 3280 1.2809 3328 1.28086 3202 1.28082 3319 1.28077 3382 1.28073 3321 1.28069 3335 1.28065 3261 1.28061 3377 1.28057 3248 1.28053 3250 1.28049 3249 1.28045 3326 1.2804 3341 1.28036 3260 1.28032 3242 1.28028 3300 1.28024 3269 1.2802 3325 1.28016 3299 1.28012 3233 1.28008 3343 1.28003 3165 1.27999 3299 1.27995 3192 1.27991 3339 1.27987 3205 1.27983 3230 1.27979 3267 1.27975 3274 1.27971 3225 1.27966 3354 1.27962 3251 1.27958 3303 1.27954 3333 1.2795 3219 1.27946 3385 1.27942 3319 1.27938 3346 1.27934 3341 1.2793 3367 1.27925 3307 1.27921 3480 1.27917 3385 1.27913 3340 1.27909 3497 1.27905 3380 1.27901 3528 1.27897 3543 1.27893 3530 1.27888 3688 1.27884 3654 1.2788 3728 1.27876 3668 1.27872 3840 1.27868 3835 1.27864 3997 1.2786 4026 1.27856 4172 1.27851 4330 1.27847 4329 1.27843 4555 1.27839 4788 1.27835 4927 1.27831 5006 1.27827 5078 1.27823 5319 1.27819 5351 1.27814 5537 1.2781 5716 1.27806 5951 1.27802 5876 1.27798 5990 1.27794 6134 1.2779 6265 1.27786 6224 1.27782 6209 1.27778 6086 1.27773 6010 1.27769 5774 1.27765 5788 1.27761 5778 1.27757 5627 1.27753 5409 1.27749 5360 1.27745 5056 1.27741 4906 1.27736 4896 1.27732 4535 1.27728 4563 1.27724 4495 1.2772 4419 1.27716 4149 1.27712 4154 1.27708 4010 1.27704 3925 1.27699 3904 1.27695 3821 1.27691 3773 1.27687 3668 1.27683 3635 1.27679 3456 1.27675 3567 1.27671 3589 1.27667 3348 1.27662 3364 1.27658 3347 1.27654 3365 1.2765 3239 1.27646 3316 1.27642 3307 1.27638 3159 1.27634 3155 1.2763 3069 1.27626 3214 1.27621 3139 1.27617 3223 1.27613 3079 1.27609 3019 1.27605 3091 1.27601 3036 1.27597 2945 1.27593 3056 1.27589 2883 1.27584 3094 1.2758 2944 1.27576 2951 1.27572 2915 1.27568 2893 1.27564 2942 1.2756 2855 1.27556 2827 1.27552 2907 1.27547 2890 1.27543 3055 1.27539 2829 1.27535 2840 1.27531 2809 1.27527 2826 1.27523 2805 1.27519 2820 1.27515 2843 1.2751 2789 1.27506 2792 1.27502 2852 1.27498 2820 1.27494 2800 1.2749 2812 1.27486 2789 1.27482 2817 1.27478 2867 1.27474 2780 1.27469 2875 1.27465 2792 1.27461 2852 1.27457 2909 1.27453 2842 1.27449 2667 1.27445 2832 1.27441 2816 1.27437 2772 1.27432 2855 1.27428 2837 1.27424 2721 1.2742 2739 1.27416 2768 1.27412 2697 1.27408 2883 1.27404 2682 1.274 2822 1.27395 2810 1.27391 2780 1.27387 2783 1.27383 2806 1.27379 2833 1.27375 2773 1.27371 2787 1.27367 2766 1.27363 2759 1.27358 2775 1.27354 2688 1.2735 2725 1.27346 2862 1.27342 2710 1.27338 2715 1.27334 2658 1.2733 2761 1.27326 2743 1.27322 2770 1.27317 2804 1.27313 2844 1.27309 2874 1.27305 2795 1.27301 2780 1.27297 2790 1.27293 2818 1.27289 2908 1.27285 2961 1.2728 2934 1.27276 3029 1.27272 3046 1.27268 3021 1.27264 3139 1.2726 3259 1.27256 3228 1.27252 3356 1.27248 3326 1.27243 3498 1.27239 3515 1.27235 3697 1.27231 3918 1.27227 4072 1.27223 4148 1.27219 4436 1.27215 4617 1.27211 4770 1.27206 5093 1.27202 5205 1.27198 5766 1.27194 5862 1.2719 6030 1.27186 6450 1.27182 6590 1.27178 6838 1.27174 7088 1.2717 7381 1.27165 7334 1.27161 7492 1.27157 7729 1.27153 7877 1.27149 7780 1.27145 7760 1.27141 7630 1.27137 7566 1.27133 7528 1.27128 7063 1.27124 7028 1.2712 6653 1.27116 6320 1.27112 6036 1.27108 5818 1.27104 5743 1.271 5396 1.27096 5037 1.27091 4828 1.27087 4682 1.27083 4363 1.27079 4129 1.27075 4009 1.27071 3936 1.27067 3652 1.27063 3600 1.27059 3419 1.27054 3333 1.2705 3232 1.27046 3211 1.27042 3150 1.27038 2940 1.27034 2873 1.2703 2878 1.27026 2806 1.27022 2758 1.27018 2595 1.27013 2607 1.27009 2595 1.27005 2668 1.27001 2630 1.26997 2520 1.26993 2493 1.26989 2489 1.26985 2421 1.26981 2438 1.26976 2402 1.26972 2410 1.26968 2401 1.26964 2252 1.2696 2314 1.26956 2270 1.26952 2293 1.26948 2305 1.26944 2222 1.26939 2337 1.26935 2225 1.26931 2220 1.26927 2268 1.26923 2193 1.26919 2194 1.26915 2155 1.26911 2193 1.26907 2221 1.26902 2215 1.26898 2129 1.26894 2055 1.2689 2151 1.26886 2094 1.26882 2103 1.26878 2102 1.26874 2190 1.2687 2108 1.26866 2155 1.26861 2034 1.26857 2052 1.26853 2034 1.26849 2157 1.26845 2037 1.26841 2103 1.26837 2087 1.26833 2130 1.26829 2046 1.26824 2094 1.2682 2082 1.26816 2140 1.26812 2082 1.26808 2030 1.26804 2106 1.268 2104 1.26796 2018 1.26792 2064 1.26787 2094 1.26783 2064 1.26779 2081 1.26775 1935 1.26771 2020 1.26767 2080 1.26763 2023 1.26759 2065 1.26755 2045 1.2675 2078 1.26746 2133 1.26742 2109 1.26738 1977 1.26734 2035 1.2673 2015 1.26726 2042 1.26722 1964 1.26718 2149 1.26714 2083 1.26709 1997 1.26705 1961 1.26701 1989 1.26697 2048 1.26693 2042 1.26689 2021 1.26685 2094 1.26681 2021 1.26677 1954 1.26672 2017 1.26668 1985 1.26664 2021 1.2666 2099 1.26656 2040 1.26652 2016 1.26648 1990 1.26644 2028 1.2664 1986 1.26635 2025 1.26631 1930 1.26627 2019 1.26623 2037 1.26619 2056 1.26615 2055 1.26611 2012 1.26607 2004 1.26603 2122 1.26598 1973 1.26594 1997 1.2659 2078 1.26586 1981 1.26582 1948 1.26578 C 1s/4 PNB80 2015 10 14 9 41 26 0 14 Casa Info Follows 1 Calib M = 280.821 A = 284.6 Regions Comps BE ADD 0 1 CASA region (*C 1s*) (*Shirley*) 1186.69 1216.69 0.278 2 0 0 299 542 275 9.3 (*C 1s*) 12.011 0 3 CASA comp (*C 1s*) (*GL(30)*) Area 350.12856 0.001 10000000 -1 1 MFWHM 1.5456846 0.4 10 -1 1 Position 1205.9592 1186.69 1216.69 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) CASA comp (*C 1s*) (*GL(30)*) Area 245.85622 0.001 10000000 -1 1 MFWHM 2.2065051 0.4 10 -1 1 Position 1204.6462 1186.69 1216.69 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) CASA comp (*C 1s*) (*GL(30)*) Area 130.75162 0.001 10000000 -1 1 MFWHM 1.9574638 0.57999403 14.499851 -1 1 Position 1201.6007 1186.69 1216.69 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) pnb.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 782 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 260 Charge Neutraliser :On Acquired On :15/10/14 09:41:26 XPS 55 6 0 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 C 1s -1 Kinetic Energy eV 1186.69 0.1 2 Intensity d Transmission d pulse counting 0.2597 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 602 731 1538 1.23374 1.24606 819 1.24606 844 1.24602 845 1.24598 825 1.24594 827 1.2459 852 1.24586 915 1.24581 862 1.24577 805 1.24573 921 1.24569 897 1.24565 835 1.24561 837 1.24557 868 1.24553 839 1.24549 884 1.24544 859 1.2454 841 1.24536 836 1.24532 858 1.24528 824 1.24524 801 1.2452 824 1.24516 806 1.24512 837 1.24507 818 1.24503 827 1.24499 837 1.24495 819 1.24491 842 1.24487 829 1.24483 783 1.24479 814 1.24475 778 1.24471 864 1.24466 783 1.24462 893 1.24458 820 1.24454 836 1.2445 804 1.24446 842 1.24442 826 1.24438 845 1.24434 836 1.24429 839 1.24425 843 1.24421 868 1.24417 889 1.24413 854 1.24409 822 1.24405 811 1.24401 762 1.24397 847 1.24392 826 1.24388 879 1.24384 860 1.2438 820 1.24376 834 1.24372 853 1.24368 866 1.24364 836 1.2436 836 1.24355 823 1.24351 826 1.24347 792 1.24343 829 1.24339 822 1.24335 806 1.24331 858 1.24327 844 1.24323 881 1.24319 835 1.24314 803 1.2431 816 1.24306 844 1.24302 882 1.24298 781 1.24294 826 1.2429 832 1.24286 864 1.24282 852 1.24277 839 1.24273 810 1.24269 840 1.24265 817 1.24261 809 1.24257 824 1.24253 834 1.24249 831 1.24245 824 1.2424 841 1.24236 837 1.24232 818 1.24228 842 1.24224 829 1.2422 814 1.24216 857 1.24212 776 1.24208 812 1.24203 812 1.24199 784 1.24195 815 1.24191 814 1.24187 797 1.24183 764 1.24179 824 1.24175 777 1.24171 809 1.24167 860 1.24162 816 1.24158 830 1.24154 811 1.2415 818 1.24146 790 1.24142 825 1.24138 789 1.24134 848 1.2413 810 1.24125 854 1.24121 833 1.24117 866 1.24113 878 1.24109 846 1.24105 783 1.24101 796 1.24097 814 1.24093 817 1.24088 847 1.24084 795 1.2408 834 1.24076 839 1.24072 823 1.24068 795 1.24064 785 1.2406 880 1.24056 915 1.24051 832 1.24047 859 1.24043 933 1.24039 907 1.24035 859 1.24031 950 1.24027 943 1.24023 932 1.24019 958 1.24015 1053 1.2401 903 1.24006 929 1.24002 1005 1.23998 994 1.23994 947 1.2399 981 1.23986 977 1.23982 961 1.23978 977 1.23973 964 1.23969 937 1.23965 946 1.23961 952 1.23957 919 1.23953 941 1.23949 896 1.23945 942 1.23941 916 1.23936 949 1.23932 921 1.23928 895 1.23924 925 1.2392 952 1.23916 1021 1.23912 987 1.23908 1028 1.23904 1055 1.23899 1008 1.23895 1085 1.23891 1064 1.23887 1103 1.23883 1084 1.23879 1113 1.23875 1174 1.23871 1174 1.23867 1206 1.23863 1267 1.23858 1309 1.23854 1227 1.2385 1297 1.23846 1358 1.23842 1362 1.23838 1467 1.23834 1427 1.2383 1470 1.23826 1400 1.23821 1538 1.23817 1531 1.23813 1382 1.23809 1317 1.23805 1365 1.23801 1368 1.23797 1233 1.23793 1221 1.23789 1132 1.23784 1084 1.2378 1064 1.23776 983 1.23772 987 1.23768 946 1.23764 909 1.2376 881 1.23756 858 1.23752 845 1.23747 835 1.23743 869 1.23739 798 1.23735 792 1.23731 793 1.23727 801 1.23723 830 1.23719 784 1.23715 817 1.23711 787 1.23706 798 1.23702 817 1.23698 795 1.23694 766 1.2369 766 1.23686 818 1.23682 823 1.23678 773 1.23674 829 1.23669 805 1.23665 818 1.23661 818 1.23657 789 1.23653 805 1.23649 758 1.23645 832 1.23641 818 1.23637 825 1.23632 784 1.23628 850 1.23624 822 1.2362 820 1.23616 804 1.23612 839 1.23608 835 1.23604 794 1.236 788 1.23595 827 1.23591 837 1.23587 826 1.23583 810 1.23579 796 1.23575 814 1.23571 791 1.23567 779 1.23563 820 1.23559 893 1.23554 818 1.2355 808 1.23546 819 1.23542 854 1.23538 731 1.23534 823 1.2353 849 1.23526 775 1.23522 785 1.23517 782 1.23513 755 1.23509 807 1.23505 809 1.23501 842 1.23497 817 1.23493 834 1.23489 779 1.23485 850 1.2348 756 1.23476 795 1.23472 803 1.23468 768 1.23464 818 1.2346 849 1.23456 839 1.23452 832 1.23448 783 1.23443 780 1.23439 798 1.23435 777 1.23431 804 1.23427 788 1.23423 829 1.23419 824 1.23415 848 1.23411 786 1.23407 805 1.23402 808 1.23398 800 1.23394 786 1.2339 774 1.23386 761 1.23382 864 1.23378 822 1.23374 Nb 3d/5 PNB80 2015 10 14 9 41 26 0 13 Casa Info Follows 1 Calib M = 280.821 A = 284.6 BE ADD 0 1 CASA region (*Nb 3d*) (*Shirley*) 1273.9577 1282.7709 2.921 2 0 0 299 542 275 9.3 (*Nb 3d*) 92.9064 0 2 CASA comp (*Nb 3d*) (*GL(30)*) Area 3372.253 0.001 10000000 -1 1 MFWHM 1.4696595 0.32 8 -1 1 Position 1279.314 1272.911 1285.911 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) CASA comp (*Nb 3d*) (*GL(30)*) Area 2097.0409 0.001 10000000 -1 1 MFWHM 1.3949397 0.32 8 -1 1 Position 1276.5509 1272.911 1285.911 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) pnb.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 1200 Sweeps: 20 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 458 Charge Neutraliser :On Acquired On :15/10/14 09:41:26 XPS 55 6 0 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3d -1 Kinetic Energy eV 1276.69 0.1 2 Intensity d Transmission d pulse counting 0.458 20 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 262 662 20435 1.20732 1.2118 2180 1.2118 2229 1.21177 2159 1.21173 2086 1.2117 2114 1.21166 2068 1.21163 2093 1.21159 1987 1.21156 1962 1.21152 1980 1.21149 1981 1.21146 1908 1.21142 1913 1.21139 1876 1.21135 1838 1.21132 1809 1.21128 1846 1.21125 1860 1.21121 1979 1.21118 1966 1.21115 2102 1.21111 2184 1.21108 2543 1.21104 2743 1.21101 3326 1.21097 3883 1.21094 4604 1.2109 5535 1.21087 6786 1.21084 7818 1.2108 9365 1.21077 10458 1.21073 11634 1.2107 12767 1.21066 13270 1.21063 13950 1.21059 14268 1.21056 13979 1.21053 13404 1.21049 13048 1.21046 11909 1.21042 11146 1.21039 10075 1.21035 8702 1.21032 7673 1.21029 6718 1.21025 5833 1.21022 5103 1.21018 4342 1.21015 4104 1.21011 4004 1.21008 4206 1.21004 4776 1.21001 5653 1.20998 6772 1.20994 8159 1.20991 9911 1.20987 11737 1.20984 13988 1.2098 15733 1.20977 17294 1.20973 18917 1.2097 19644 1.20967 20237 1.20963 20435 1.2096 19672 1.20956 18961 1.20953 17850 1.20949 16313 1.20946 14803 1.20942 13130 1.20939 11167 1.20936 9649 1.20932 7981 1.20929 6731 1.20925 5359 1.20922 4346 1.20918 3478 1.20915 2778 1.20911 2243 1.20908 1863 1.20905 1518 1.20901 1218 1.20898 1120 1.20894 996 1.20891 957 1.20887 979 1.20884 828 1.2088 860 1.20877 763 1.20874 754 1.2087 735 1.20867 817 1.20863 747 1.2086 782 1.20856 733 1.20853 736 1.20849 702 1.20846 697 1.20843 708 1.20839 705 1.20836 700 1.20832 674 1.20829 677 1.20825 721 1.20822 662 1.20819 696 1.20815 712 1.20812 705 1.20808 686 1.20805 725 1.20801 678 1.20798 701 1.20794 697 1.20791 762 1.20788 729 1.20784 725 1.20781 749 1.20777 797 1.20774 800 1.2077 732 1.20767 724 1.20763 755 1.2076 797 1.20757 772 1.20753 767 1.2075 863 1.20746 815 1.20743 763 1.20739 811 1.20736 808 1.20732 Si 2p/6 PNB80 2015 10 14 9 41 26 0 10 Casa Info Follows 1 Calib M = 280.821 A = 284.6 BE ADD 0 0 0 pnb.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 799 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 397 Charge Neutraliser :On Acquired On :15/10/14 09:41:26 XPS 55 6 0 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Si 2p -1 Kinetic Energy eV 1376.69 0.1 2 Intensity d Transmission d pulse counting 0.3974 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 285 405 1.19156 1.19218 358 1.19218 312 1.19218 329 1.19217 300 1.19217 314 1.19217 316 1.19216 341 1.19216 288 1.19216 324 1.19215 297 1.19215 320 1.19215 339 1.19214 325 1.19214 345 1.19214 314 1.19213 318 1.19213 308 1.19213 329 1.19213 316 1.19212 298 1.19212 332 1.19212 321 1.19211 308 1.19211 320 1.19211 329 1.1921 331 1.1921 311 1.1921 347 1.19209 291 1.19209 311 1.19209 324 1.19209 317 1.19208 347 1.19208 332 1.19208 286 1.19207 298 1.19207 352 1.19207 301 1.19206 311 1.19206 338 1.19206 337 1.19205 305 1.19205 336 1.19205 353 1.19205 285 1.19204 336 1.19204 304 1.19204 314 1.19203 344 1.19203 318 1.19203 314 1.19202 345 1.19202 334 1.19202 315 1.19201 299 1.19201 324 1.19201 301 1.19201 309 1.192 335 1.192 297 1.192 352 1.19199 295 1.19199 310 1.19199 302 1.19198 322 1.19198 332 1.19198 302 1.19197 303 1.19197 307 1.19197 294 1.19196 313 1.19196 303 1.19196 351 1.19196 315 1.19195 344 1.19195 342 1.19195 357 1.19194 359 1.19194 330 1.19194 317 1.19193 329 1.19193 295 1.19193 346 1.19192 309 1.19192 334 1.19192 331 1.19192 362 1.19191 317 1.19191 315 1.19191 355 1.1919 354 1.1919 405 1.1919 376 1.19189 335 1.19189 349 1.19189 365 1.19188 345 1.19188 330 1.19188 371 1.19188 356 1.19187 352 1.19187 340 1.19187 392 1.19186 310 1.19186 356 1.19186 356 1.19185 313 1.19185 340 1.19185 367 1.19184 320 1.19184 296 1.19184 339 1.19184 344 1.19183 355 1.19183 330 1.19183 343 1.19182 369 1.19182 345 1.19182 318 1.19181 370 1.19181 321 1.19181 348 1.1918 348 1.1918 343 1.1918 354 1.1918 334 1.19179 319 1.19179 332 1.19179 316 1.19178 352 1.19178 355 1.19178 345 1.19177 330 1.19177 296 1.19177 286 1.19176 329 1.19176 312 1.19176 336 1.19176 329 1.19175 318 1.19175 374 1.19175 352 1.19174 313 1.19174 338 1.19174 374 1.19173 315 1.19173 308 1.19173 319 1.19172 323 1.19172 294 1.19172 298 1.19171 310 1.19171 350 1.19171 314 1.19171 315 1.1917 305 1.1917 316 1.1917 356 1.19169 372 1.19169 311 1.19169 354 1.19168 333 1.19168 346 1.19168 303 1.19167 335 1.19167 306 1.19167 319 1.19167 336 1.19166 352 1.19166 297 1.19166 314 1.19165 336 1.19165 312 1.19165 319 1.19164 331 1.19164 391 1.19164 342 1.19163 319 1.19163 341 1.19163 323 1.19163 347 1.19162 349 1.19162 306 1.19162 332 1.19161 350 1.19161 336 1.19161 375 1.1916 369 1.1916 345 1.1916 318 1.19159 311 1.19159 341 1.19159 316 1.19159 337 1.19158 313 1.19158 312 1.19158 335 1.19157 345 1.19157 331 1.19157 307 1.19156 352 1.19156 wide/1 PNB300 2015 10 14 12 26 47 0 10 Casa Info Follows 1 Calib M = 280.738 A = 284.6 BE ADD 0 0 0 pnb300.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 160 Acqn. Time(s): 603 Sweeps: 5 Anode:Mono(Al (Mono))(156 W) Step(meV): 1000.0 Dwell Time(ms): 100 Charge Neutraliser :On Acquired On :15/10/14 12:26:47 XPS 55 1 1 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 160 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Wide None -1 Kinetic Energy eV 286.69 1 2 Intensity d Transmission d pulse counting 0.1 5 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 2412 0 1475 4.41569 8.42235 288 8.42235 325 8.38839 299 8.35442 296 8.32045 312 8.28649 309 8.25252 273 8.21856 309 8.18459 314 8.15063 279 8.11666 290 8.0827 281 8.04873 307 8.01476 312 7.9808 298 7.94683 301 7.91287 287 7.8789 291 7.84494 308 7.81097 282 7.77701 301 7.74304 317 7.70907 304 7.67511 285 7.64114 314 7.60718 300 7.57321 303 7.53925 278 7.50528 312 7.47131 298 7.43735 297 7.40338 300 7.36942 316 7.33545 275 7.30149 291 7.26752 289 7.23356 315 7.19959 285 7.16562 314 7.13166 315 7.09769 295 7.06373 285 7.02976 291 7.00512 267 6.99202 277 6.97893 273 6.96583 298 6.95273 315 6.93963 301 6.92653 304 6.91343 275 6.90033 292 6.88723 301 6.87414 298 6.86104 321 6.84794 317 6.83484 294 6.82174 282 6.80864 298 6.79554 296 6.78244 313 6.76935 310 6.75625 292 6.74315 310 6.73005 274 6.71695 316 6.70385 300 6.69075 296 6.67765 308 6.66456 283 6.65146 298 6.63836 287 6.62526 308 6.61216 301 6.59906 304 6.58596 318 6.57286 326 6.55976 294 6.54667 314 6.53357 308 6.52047 298 6.50737 297 6.49427 272 6.48117 314 6.46807 318 6.45497 316 6.44188 312 6.42878 312 6.41568 299 6.40258 314 6.38948 310 6.37638 287 6.36328 323 6.35018 308 6.33709 299 6.32399 311 6.31089 309 6.29779 341 6.28469 298 6.27159 317 6.25849 294 6.24539 329 6.2323 359 6.2192 364 6.2061 328 6.193 297 6.1799 318 6.1668 313 6.1537 283 6.1406 287 6.1275 301 6.11441 356 6.10131 318 6.08821 308 6.07511 299 6.06201 288 6.04891 318 6.03581 316 6.02271 313 6.00962 334 5.99652 343 5.98342 322 5.97032 327 5.95722 375 5.94412 340 5.93102 343 5.91792 312 5.90483 325 5.89173 331 5.87863 312 5.86553 313 5.85243 349 5.83933 331 5.82623 365 5.81313 345 5.80004 338 5.78694 338 5.77384 305 5.76074 352 5.74764 316 5.73454 343 5.72144 325 5.70834 327 5.69524 311 5.68215 309 5.66905 361 5.65595 286 5.64285 327 5.62975 348 5.61665 299 5.60355 332 5.59045 319 5.57736 323 5.56426 325 5.55116 326 5.53806 359 5.52496 336 5.51186 352 5.49876 362 5.48566 378 5.47257 352 5.45947 352 5.44637 355 5.43327 360 5.42017 339 5.40707 347 5.39397 341 5.38087 325 5.36778 321 5.35468 358 5.34158 340 5.33457 338 5.33071 380 5.32684 363 5.32297 387 5.31911 368 5.31524 375 5.31137 356 5.30751 348 5.30364 367 5.29978 362 5.29591 352 5.29204 356 5.28818 354 5.28431 356 5.28044 369 5.27658 366 5.27271 386 5.26885 372 5.26498 366 5.26111 347 5.25725 385 5.25338 326 5.24951 354 5.24565 365 5.24178 344 5.23792 386 5.23405 373 5.23018 384 5.22632 381 5.22245 400 5.21858 385 5.21472 370 5.21085 375 5.20699 382 5.20312 382 5.19925 369 5.19539 399 5.19152 392 5.18765 414 5.18379 376 5.17992 395 5.17606 379 5.17219 362 5.16832 377 5.16446 373 5.16059 366 5.15672 332 5.15286 356 5.14899 355 5.14513 371 5.14126 355 5.13739 384 5.13353 378 5.12966 394 5.12579 419 5.12193 454 5.11806 468 5.1142 505 5.11033 514 5.10646 498 5.1026 456 5.09873 427 5.09486 397 5.091 372 5.08713 360 5.08327 344 5.0794 349 5.07553 325 5.07167 305 5.0678 299 5.06393 277 5.06007 292 5.0562 287 5.05234 285 5.04847 282 5.0446 278 5.04074 258 5.03687 266 5.033 285 5.02914 267 5.02527 282 5.02141 267 5.01754 277 5.01367 290 5.00981 291 5.00594 280 5.00207 293 4.99821 288 4.99434 287 4.99048 302 4.98661 264 4.98274 260 4.97888 293 4.97501 271 4.97114 288 4.96728 321 4.96341 287 4.95955 285 4.95568 287 4.95181 304 4.94795 293 4.94408 305 4.94021 285 4.93635 285 4.93248 300 4.92862 287 4.92475 316 4.92088 312 4.91702 283 4.91315 316 4.90928 306 4.90542 299 4.90155 304 4.89769 290 4.89382 301 4.88995 293 4.88609 293 4.88222 308 4.87835 334 4.87449 309 4.87062 298 4.86676 335 4.86289 315 4.85902 314 4.85516 312 4.85129 302 4.84742 313 4.84356 324 4.83969 298 4.83582 302 4.83196 310 4.82809 291 4.82423 292 4.82036 322 4.81649 314 4.81263 299 4.80876 327 4.80489 309 4.80103 322 4.79716 355 4.7933 338 4.78943 292 4.78556 296 4.7817 315 4.77783 362 4.77396 291 4.7701 325 4.76623 326 4.76237 339 4.7585 298 4.75463 304 4.75077 308 4.7469 313 4.74303 325 4.73917 338 4.7353 315 4.73144 335 4.72757 333 4.7237 308 4.71984 313 4.71597 319 4.7121 283 4.70824 336 4.70437 300 4.70051 311 4.69664 304 4.69277 320 4.68891 338 4.68504 344 4.68117 318 4.67731 353 4.67344 338 4.66958 325 4.66571 315 4.66184 340 4.65798 349 4.65411 354 4.65024 325 4.64638 329 4.64251 340 4.63865 340 4.63478 330 4.63091 343 4.62705 340 4.62318 340 4.61931 313 4.61545 354 4.61158 346 4.60772 333 4.60385 331 4.59998 339 4.59612 330 4.59225 364 4.58838 346 4.58452 347 4.58065 340 4.57679 335 4.57292 347 4.56905 318 4.56519 331 4.56132 328 4.55745 338 4.55359 336 4.54972 330 4.54586 349 4.54199 359 4.53812 369 4.53426 361 4.53039 352 4.52906 357 4.52854 347 4.52803 388 4.52752 362 4.52701 337 4.52649 370 4.52598 366 4.52547 340 4.52495 377 4.52444 337 4.52393 375 4.52341 344 4.5229 341 4.52239 344 4.52188 364 4.52136 367 4.52085 355 4.52034 379 4.51982 372 4.51931 407 4.5188 352 4.51828 384 4.51777 337 4.51726 328 4.51675 359 4.51623 360 4.51572 354 4.51521 333 4.51469 346 4.51418 371 4.51367 345 4.51315 368 4.51264 364 4.51213 343 4.51162 327 4.5111 342 4.51059 383 4.51008 375 4.50956 336 4.50905 337 4.50854 341 4.50803 336 4.50751 350 4.507 377 4.50649 367 4.50597 362 4.50546 395 4.50495 377 4.50443 399 4.50392 368 4.50341 359 4.50289 409 4.50238 351 4.50187 350 4.50136 405 4.50084 388 4.50033 357 4.49982 390 4.4993 375 4.49879 391 4.49828 386 4.49777 366 4.49725 385 4.49674 379 4.49623 374 4.49571 380 4.4952 370 4.49469 388 4.49417 405 4.49366 429 4.49315 405 4.49264 386 4.49212 382 4.49161 391 4.4911 389 4.49058 411 4.49007 408 4.48956 400 4.48904 392 4.48853 369 4.48802 412 4.48751 399 4.48699 386 4.48648 367 4.48597 392 4.48545 419 4.48494 390 4.48443 385 4.48391 404 4.4834 414 4.48289 410 4.48238 389 4.48186 396 4.48135 404 4.48084 382 4.48032 392 4.47981 417 4.4793 399 4.47878 408 4.47827 414 4.47776 450 4.47725 405 4.47673 432 4.47622 450 4.47571 399 4.47519 416 4.47468 434 4.47417 407 4.47365 426 4.47314 404 4.47263 416 4.47212 439 4.4716 428 4.47109 412 4.47058 424 4.47006 410 4.46955 451 4.46904 421 4.46852 405 4.46801 406 4.4675 469 4.46699 402 4.46647 430 4.46596 380 4.46545 392 4.46493 474 4.46442 456 4.46391 435 4.46339 456 4.46288 428 4.46237 416 4.46186 440 4.46134 442 4.46083 428 4.46032 439 4.4598 481 4.45929 419 4.45878 447 4.45826 435 4.45775 435 4.45724 460 4.45673 462 4.45621 421 4.4557 455 4.45519 467 4.45467 480 4.45416 474 4.45365 425 4.45313 425 4.45262 418 4.45211 424 4.4516 425 4.45108 455 4.45057 474 4.45006 447 4.44954 409 4.44903 432 4.44852 461 4.448 453 4.44749 457 4.44698 468 4.44647 465 4.44595 449 4.44544 468 4.44493 455 4.44441 472 4.4439 481 4.44339 464 4.44287 456 4.44236 448 4.44185 455 4.44134 439 4.44082 461 4.44031 469 4.4398 440 4.43928 495 4.43877 470 4.43826 470 4.43775 454 4.43723 466 4.43672 492 4.43621 522 4.43569 463 4.43518 440 4.43467 484 4.43415 476 4.43364 457 4.43313 469 4.43262 475 4.4321 472 4.43159 484 4.43108 511 4.43056 465 4.43005 475 4.42954 485 4.42902 482 4.42851 478 4.428 463 4.42748 480 4.42697 493 4.42646 483 4.42595 466 4.42543 497 4.42492 486 4.42441 491 4.42389 483 4.42338 460 4.42287 511 4.42236 498 4.42184 491 4.42133 477 4.42082 523 4.4203 541 4.41979 514 4.41928 509 4.41876 494 4.41825 510 4.41774 519 4.41723 482 4.41671 504 4.4162 492 4.41569 495 4.41652 534 4.41746 494 4.41841 497 4.41936 542 4.4203 528 4.42125 500 4.4222 518 4.42315 555 4.42409 521 4.42504 508 4.42599 550 4.42694 525 4.42788 503 4.42883 499 4.42978 503 4.43073 556 4.43167 566 4.43262 538 4.43357 513 4.43451 535 4.43546 524 4.43641 554 4.43736 539 4.4383 532 4.43925 557 4.4402 558 4.44115 551 4.44209 522 4.44304 607 4.44399 562 4.44494 540 4.44588 538 4.44683 552 4.44778 513 4.44873 529 4.44967 535 4.45062 551 4.45157 521 4.45251 553 4.45346 542 4.45441 529 4.45536 520 4.4563 518 4.45725 535 4.4582 562 4.45915 553 4.46009 571 4.46104 547 4.46199 547 4.46294 574 4.46388 566 4.46483 567 4.46578 579 4.46672 576 4.46767 516 4.46862 532 4.46957 568 4.47051 573 4.47146 597 4.47241 541 4.47336 539 4.4743 515 4.47525 517 4.4762 518 4.47715 486 4.47809 499 4.47904 491 4.47999 468 4.48094 470 4.48188 593 4.48283 904 4.48378 1419 4.48472 1475 4.48567 949 4.48662 472 4.48757 417 4.48851 401 4.48946 405 4.49041 425 4.49136 425 4.4923 445 4.49325 416 4.4942 391 4.49515 435 4.49609 434 4.49704 423 4.49799 423 4.49893 445 4.49988 414 4.50083 409 4.50178 407 4.50272 409 4.50367 436 4.50462 416 4.50557 424 4.50651 431 4.50746 431 4.50841 436 4.50936 457 4.5103 441 4.51125 428 4.5122 444 4.51314 444 4.51409 464 4.51504 455 4.51599 444 4.51693 460 4.51788 443 4.51883 457 4.51978 445 4.52072 400 4.52167 456 4.52262 440 4.52357 459 4.52451 476 4.52546 473 4.52641 484 4.52736 449 4.5283 455 4.52925 425 4.5302 429 4.53114 445 4.53209 446 4.53304 440 4.53399 438 4.53493 458 4.53588 465 4.53683 478 4.53778 492 4.53872 547 4.53967 534 4.54062 528 4.54157 493 4.54251 519 4.54346 508 4.54441 427 4.54535 474 4.5463 450 4.54725 440 4.5482 473 4.54914 457 4.55009 441 4.55104 433 4.55199 439 4.55293 414 4.55388 411 4.55483 447 4.55578 459 4.55764 432 4.5599 440 4.56217 438 4.56443 441 4.56669 423 4.56896 446 4.57122 437 4.57349 423 4.57575 446 4.57801 450 4.58028 447 4.58254 425 4.58481 480 4.58707 467 4.58933 445 4.5916 434 4.59386 440 4.59613 481 4.59839 442 4.60065 426 4.60292 434 4.60518 455 4.60745 459 4.60971 472 4.61197 463 4.61424 428 4.6165 466 4.61877 446 4.62103 486 4.62329 477 4.62556 446 4.62782 482 4.63009 475 4.63235 455 4.63461 457 4.63688 443 4.63914 453 4.64141 451 4.64367 451 4.64593 480 4.6482 455 4.65046 439 4.65273 455 4.65499 447 4.65725 453 4.65952 446 4.66178 453 4.66405 475 4.66631 477 4.66857 460 4.67084 465 4.6731 430 4.67537 468 4.67763 475 4.67989 488 4.68216 449 4.68442 470 4.68669 479 4.68895 501 4.69121 466 4.69348 499 4.69574 485 4.69801 517 4.70027 468 4.70253 465 4.7048 474 4.70706 466 4.70933 506 4.71159 519 4.71385 485 4.71612 506 4.71838 592 4.72065 742 4.72291 830 4.72517 781 4.72744 634 4.7297 507 4.73197 480 4.73423 465 4.73649 413 4.73876 396 4.74102 396 4.74329 405 4.74555 366 4.74781 401 4.75008 442 4.75234 543 4.75461 724 4.75687 990 4.75913 1017 4.7614 777 4.76366 528 4.76593 422 4.76819 370 4.77045 306 4.77272 315 4.77498 291 4.77725 286 4.77951 299 4.78177 264 4.78404 286 4.7863 273 4.78857 260 4.79083 291 4.79309 282 4.79536 291 4.79762 290 4.79989 285 4.80215 272 4.80441 270 4.80668 287 4.80894 281 4.81121 264 4.81347 284 4.81573 285 4.818 259 4.82026 270 4.82253 263 4.82479 290 4.82705 269 4.82932 298 4.83158 323 4.83385 289 4.83611 307 4.83837 294 4.84064 276 4.8429 280 4.84517 291 4.84743 291 4.84969 294 4.85196 284 4.85422 261 4.85648 299 4.85875 269 4.86101 306 4.86328 294 4.86554 302 4.86781 289 4.87007 318 4.87233 285 4.8746 297 4.87686 313 4.87913 303 4.88139 310 4.88365 281 4.88592 287 4.88818 313 4.89044 298 4.89271 286 4.89497 284 4.89724 307 4.8995 315 4.90176 311 4.90403 338 4.90629 327 4.90856 301 4.91082 294 4.91308 312 4.91535 295 4.91761 285 4.91988 339 4.92214 311 4.9244 298 4.92667 302 4.92893 332 4.9312 379 4.93346 350 4.93572 348 4.93799 410 4.94025 438 4.94252 414 4.94478 342 4.94704 287 4.94931 323 4.95157 319 4.95384 293 4.9561 295 4.95836 301 4.96063 306 4.96289 310 4.96516 312 4.96742 324 4.96968 302 4.97195 307 4.97421 317 4.97648 323 4.97874 297 4.981 305 4.98327 321 4.98553 322 4.9878 316 4.99006 324 4.99232 350 4.99459 299 4.99685 327 4.99912 306 5.00138 306 5.00364 307 5.00591 314 5.00817 333 5.01044 334 5.01342 326 5.01665 329 5.01988 297 5.02311 306 5.02633 323 5.02956 288 5.03279 317 5.03601 313 5.03924 299 5.04247 284 5.0457 286 5.04892 311 5.05215 312 5.05538 328 5.05861 301 5.06183 315 5.06506 333 5.06829 330 5.07152 356 5.07474 365 5.07797 340 5.0812 347 5.08442 349 5.08765 340 5.09088 360 5.09411 354 5.09733 375 5.10056 380 5.10379 407 5.10702 369 5.11024 386 5.11347 431 5.1167 412 5.11993 341 5.12315 311 5.12638 301 5.12961 279 5.13283 286 5.13606 275 5.13929 242 5.14252 247 5.14574 321 5.14897 679 5.1522 1103 5.15543 1035 5.15865 1237 5.16188 1444 5.16511 769 5.16834 234 5.17156 86 5.17479 79 5.17802 73 5.18124 72 5.18447 72 5.1877 65 5.19093 60 5.19415 72 5.19738 66 5.20061 69 5.20384 69 5.20706 71 5.21029 63 5.21352 60 5.21675 68 5.21997 53 5.2232 81 5.22643 75 5.22965 64 5.23288 73 5.23611 70 5.23934 63 5.24256 64 5.24579 74 5.24902 59 5.25225 70 5.25547 65 5.2587 71 5.26193 70 5.26516 71 5.26838 72 5.27161 63 5.27484 68 5.27806 49 5.28129 55 5.28452 72 5.28775 72 5.29097 58 5.2942 77 5.29743 67 5.30066 66 5.30388 61 5.30711 65 5.31034 60 5.31381 60 5.31803 60 5.32226 80 5.32648 72 5.33071 70 5.33493 63 5.33916 78 5.34338 76 5.34761 64 5.35183 73 5.35606 59 5.36028 65 5.36451 80 5.36873 70 5.37296 68 5.37718 77 5.38141 59 5.38564 81 5.38986 99 5.39409 70 5.39831 66 5.40254 61 5.40676 81 5.41099 78 5.41521 69 5.41944 85 5.42366 78 5.42789 79 5.43211 80 5.43634 76 5.44056 68 5.44479 73 5.44902 82 5.45324 88 5.45747 82 5.46169 74 5.46592 73 5.47014 92 5.47437 82 5.47859 64 5.48282 60 5.48704 87 5.49127 63 5.49549 64 5.49972 77 5.50394 73 5.50817 79 5.5124 77 5.51662 86 5.52085 81 5.52507 75 5.5293 84 5.53352 86 5.53775 67 5.54197 79 5.5462 71 5.55042 78 5.55465 88 5.55887 81 5.5631 75 5.56732 81 5.57155 70 5.57578 78 5.58 84 5.58423 86 5.58845 93 5.59268 69 5.5969 74 5.60113 87 5.60535 90 5.60958 80 5.6138 82 5.61803 87 5.62225 90 5.62648 82 5.6307 93 5.63493 98 5.63916 85 5.64338 83 5.64761 81 5.65183 84 5.65606 91 5.66028 83 5.66451 88 5.66873 82 5.67296 98 5.67718 90 5.68141 89 5.68563 73 5.68986 76 5.69408 92 5.69831 76 5.70254 79 5.70676 93 5.71099 89 5.71521 91 5.71944 95 5.72366 99 5.72789 122 5.73211 113 5.73634 113 5.74056 104 5.74479 89 5.74901 96 5.75324 85 5.75746 88 5.76169 85 5.76591 87 5.77014 86 5.77437 72 5.77859 87 5.78282 85 5.78704 82 5.79127 72 5.79549 72 5.79972 71 5.80394 66 5.80817 72 5.81239 67 5.81662 66 5.82084 97 5.82507 102 5.8293 161 5.83352 207 5.83775 244 5.84197 262 5.8462 169 5.85042 80 5.85465 54 5.85887 41 5.8631 35 5.86732 38 5.87155 34 5.87577 33 5.87603 39 5.87603 28 5.87603 51 5.87603 78 5.87603 94 5.87603 74 5.87603 53 5.87603 29 5.87603 25 5.87603 17 5.87603 13 5.87603 9 5.87603 12 5.87603 14 5.87603 13 5.87603 12 5.87603 12 5.87603 32 5.87603 56 5.87603 54 5.87603 53 5.87603 49 5.87603 35 5.87603 14 5.87603 7 5.87603 1 5.87603 1 5.87603 0 5.87603 O 1s/2 PNB300 2015 10 14 12 46 18 0 13 Casa Info Follows 1 Calib M = 280.738 A = 284.6 BE ADD 0 1 CASA region (*O 1s*) (*Shirley*) 951.266 961.05666 0.78 2 0 0 299 542 275 9.3 (*O 1s*) 15.9994 0 2 CASA comp (*O 1s*) (*GL(30)*) Area 2744.8341 0.001 10000000 -1 1 MFWHM 1.4456032 0.3 7.5 -1 1 Position 956.47238 942.828 962.828 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) CASA comp (*O 1s*) (*GL(30)*) Area 261.28824 0.001 10000000 -1 1 MFWHM 1.3436606 0.29494426 7.3736065 -1 1 Position 954.73536 942.828 962.828 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) pnb300.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 666 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 332 Charge Neutraliser :On Acquired On :15/10/14 12:46:18 XPS 63 0 1 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 O 1s -1 Kinetic Energy eV 946.69 0.1 2 Intensity d Transmission d pulse counting 0.3315 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 1186 7229 1.31473 1.31659 1816 1.31659 1777 1.31658 1815 1.31657 1778 1.31656 1771 1.31655 1831 1.31654 1785 1.31653 1830 1.31652 1811 1.31651 1698 1.3165 1781 1.3165 1730 1.31649 1736 1.31648 1741 1.31647 1759 1.31646 1694 1.31645 1712 1.31644 1736 1.31643 1749 1.31642 1677 1.31641 1691 1.3164 1760 1.31639 1671 1.31638 1605 1.31637 1604 1.31637 1670 1.31636 1655 1.31635 1645 1.31634 1647 1.31633 1664 1.31632 1568 1.31631 1559 1.3163 1609 1.31629 1573 1.31628 1626 1.31627 1631 1.31626 1550 1.31625 1558 1.31624 1536 1.31623 1582 1.31623 1520 1.31622 1607 1.31621 1540 1.3162 1490 1.31619 1570 1.31618 1557 1.31617 1500 1.31616 1532 1.31615 1562 1.31614 1597 1.31613 1467 1.31612 1457 1.31611 1518 1.3161 1520 1.3161 1590 1.31609 1524 1.31608 1575 1.31607 1520 1.31606 1507 1.31605 1573 1.31604 1542 1.31603 1557 1.31602 1606 1.31601 1630 1.316 1547 1.31599 1452 1.31598 1507 1.31597 1476 1.31597 1538 1.31596 1600 1.31595 1621 1.31594 1516 1.31593 1569 1.31592 1606 1.31591 1530 1.3159 1559 1.31589 1524 1.31588 1556 1.31587 1464 1.31586 1583 1.31585 1563 1.31584 1521 1.31584 1522 1.31583 1567 1.31582 1531 1.31581 1469 1.3158 1442 1.31579 1401 1.31578 1467 1.31577 1448 1.31576 1364 1.31575 1484 1.31574 1403 1.31573 1448 1.31572 1450 1.31571 1509 1.3157 1418 1.3157 1478 1.31569 1456 1.31568 1420 1.31567 1482 1.31566 1467 1.31565 1475 1.31564 1498 1.31563 1485 1.31562 1558 1.31561 1485 1.3156 1516 1.31559 1611 1.31558 1696 1.31557 1654 1.31557 1659 1.31556 1804 1.31555 1829 1.31554 1889 1.31553 1963 1.31552 2026 1.31551 2126 1.3155 2099 1.31549 2211 1.31548 2244 1.31547 2451 1.31546 2431 1.31545 2576 1.31544 2707 1.31544 3013 1.31543 3117 1.31542 3479 1.31541 3829 1.3154 4380 1.31539 4843 1.31538 5371 1.31537 5969 1.31536 6381 1.31535 6634 1.31534 7155 1.31533 7134 1.31532 7229 1.31531 6976 1.31531 6610 1.3153 6143 1.31529 5628 1.31528 5161 1.31527 4576 1.31526 4009 1.31525 3443 1.31524 3030 1.31523 2640 1.31522 2389 1.31521 2087 1.3152 1935 1.31519 1780 1.31518 1646 1.31517 1531 1.31517 1538 1.31516 1397 1.31515 1313 1.31514 1381 1.31513 1396 1.31512 1347 1.31511 1308 1.3151 1346 1.31509 1316 1.31508 1290 1.31507 1338 1.31506 1313 1.31505 1270 1.31504 1284 1.31504 1235 1.31503 1294 1.31502 1270 1.31501 1235 1.315 1326 1.31499 1339 1.31498 1354 1.31497 1282 1.31496 1311 1.31495 1282 1.31494 1294 1.31493 1329 1.31492 1300 1.31491 1186 1.31491 1291 1.3149 1303 1.31489 1284 1.31488 1314 1.31487 1308 1.31486 1280 1.31485 1290 1.31484 1264 1.31483 1245 1.31482 1285 1.31481 1271 1.3148 1299 1.31479 1253 1.31478 1341 1.31478 1324 1.31477 1356 1.31476 1275 1.31475 1257 1.31474 1322 1.31473 Nb 3p/3 PNB300 2015 10 14 12 46 18 0 15 Casa Info Follows 1 Calib M = 280.738 A = 284.6 BE ADD 0 1 CASA region (*Nb 3p*) (*Shirley*) 1090.828 1134.828 2.63 2 0 0 299 542 275 9.3 (*Nb 3p*) 92.9064 0 4 CASA comp (*Nb 3p*) (*GL(30)*) Area 2037.4147 0.001 10000000 -1 1 MFWHM 2.4538087 0.52 13 -1 1 Position 1121.4501 1090.828 1134.828 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 882.03793 0.001 10000000 -1 1 MFWHM 2.236004 0.52 13 -1 1 Position 1105.8954 1090.828 1134.828 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 641.88024 0.001 10000000 -1 1 MFWHM 5.9875962 0.56856036 14.214009 -1 1 Position 1123.4933 1090.828 1134.828 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 612.79292 0.001 10000000 -1 1 MFWHM 4.0767513 0.75574692 18.893673 -1 1 Position 1107.058 1090.828 1134.828 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) pnb300.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 2871 Sweeps: 50 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 130 Charge Neutraliser :On Acquired On :15/10/14 12:46:18 XPS 63 0 1 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3p -1 Kinetic Energy eV 1094.69 0.1 2 Intensity d Transmission d pulse counting 0.1302 50 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 882 1646 7653 1.26578 1.28386 3081 1.28386 3022 1.28381 3115 1.28377 3118 1.28373 3120 1.28369 3085 1.28365 3080 1.28361 3104 1.28357 3198 1.28353 3179 1.28349 3055 1.28344 3144 1.2834 3178 1.28336 3129 1.28332 3099 1.28328 3076 1.28324 3098 1.2832 3132 1.28316 3103 1.28312 3042 1.28307 3092 1.28303 3150 1.28299 3114 1.28295 3094 1.28291 3046 1.28287 3077 1.28283 3148 1.28279 3124 1.28275 3012 1.2827 3044 1.28266 3133 1.28262 3057 1.28258 2959 1.28254 3031 1.2825 3043 1.28246 3047 1.28242 2977 1.28238 2940 1.28234 3009 1.28229 2978 1.28225 2919 1.28221 2876 1.28217 3061 1.28213 2925 1.28209 2891 1.28205 3080 1.28201 2972 1.28197 3033 1.28192 2998 1.28188 2925 1.28184 2974 1.2818 2960 1.28176 2934 1.28172 3003 1.28168 2966 1.28164 2902 1.2816 3081 1.28155 3022 1.28151 2907 1.28147 2935 1.28143 2927 1.28139 3069 1.28135 2933 1.28131 2944 1.28127 2917 1.28123 2965 1.28118 2957 1.28114 2967 1.2811 2963 1.28106 2957 1.28102 2947 1.28098 2920 1.28094 2923 1.2809 3065 1.28086 3001 1.28082 2972 1.28077 2908 1.28073 2911 1.28069 3055 1.28065 2968 1.28061 2941 1.28057 2875 1.28053 3029 1.28049 2977 1.28045 3000 1.2804 2947 1.28036 3006 1.28032 3032 1.28028 2988 1.28024 2912 1.2802 3000 1.28016 3005 1.28012 2964 1.28008 2934 1.28003 2876 1.27999 2971 1.27995 2934 1.27991 2856 1.27987 2972 1.27983 2946 1.27979 2975 1.27975 2894 1.27971 3070 1.27966 2945 1.27962 2965 1.27958 2991 1.27954 3016 1.2795 2976 1.27946 2950 1.27942 2978 1.27938 3088 1.27934 2939 1.2793 2991 1.27925 2972 1.27921 3049 1.27917 3116 1.27913 2917 1.27909 2994 1.27905 3016 1.27901 3060 1.27897 3067 1.27893 3108 1.27888 3223 1.27884 3266 1.2788 3204 1.27876 3403 1.27872 3305 1.27868 3383 1.27864 3263 1.2786 3690 1.27856 3449 1.27851 3501 1.27847 3629 1.27843 3744 1.27839 3782 1.27835 3936 1.27831 3977 1.27827 4223 1.27823 4160 1.27819 4344 1.27814 4651 1.2781 4770 1.27806 4942 1.27802 5181 1.27798 5173 1.27794 5549 1.2779 5534 1.27786 5633 1.27782 5945 1.27778 5878 1.27773 5889 1.27769 5963 1.27765 5871 1.27761 5816 1.27757 5751 1.27753 5705 1.27749 5561 1.27745 5723 1.27741 5333 1.27736 5228 1.27732 4980 1.27728 4867 1.27724 4780 1.2772 4616 1.27716 4473 1.27712 4199 1.27708 4147 1.27704 4111 1.27699 3911 1.27695 3871 1.27691 3760 1.27687 3875 1.27683 3562 1.27679 3631 1.27675 3516 1.27671 3371 1.27667 3408 1.27662 3289 1.27658 3200 1.27654 3233 1.2765 3126 1.27646 3033 1.27642 3011 1.27638 3024 1.27634 2999 1.2763 3010 1.27626 2866 1.27621 2865 1.27617 2896 1.27613 2852 1.27609 2864 1.27605 2755 1.27601 2718 1.27597 2813 1.27593 2821 1.27589 2704 1.27584 2747 1.2758 2696 1.27576 2720 1.27572 2708 1.27568 2707 1.27564 2706 1.2756 2613 1.27556 2729 1.27552 2581 1.27547 2628 1.27543 2621 1.27539 2557 1.27535 2567 1.27531 2626 1.27527 2505 1.27523 2565 1.27519 2480 1.27515 2573 1.2751 2534 1.27506 2573 1.27502 2717 1.27498 2550 1.27494 2589 1.2749 2647 1.27486 2475 1.27482 2480 1.27478 2564 1.27474 2567 1.27469 2477 1.27465 2409 1.27461 2569 1.27457 2504 1.27453 2593 1.27449 2513 1.27445 2585 1.27441 2461 1.27437 2520 1.27432 2464 1.27428 2572 1.27424 2595 1.2742 2489 1.27416 2439 1.27412 2491 1.27408 2486 1.27404 2501 1.274 2504 1.27395 2450 1.27391 2481 1.27387 2493 1.27383 2539 1.27379 2490 1.27375 2499 1.27371 2457 1.27367 2497 1.27363 2353 1.27358 2383 1.27354 2534 1.2735 2519 1.27346 2518 1.27342 2493 1.27338 2439 1.27334 2451 1.2733 2593 1.27326 2527 1.27322 2535 1.27317 2519 1.27313 2544 1.27309 2528 1.27305 2551 1.27301 2552 1.27297 2635 1.27293 2511 1.27289 2464 1.27285 2604 1.2728 2681 1.27276 2580 1.27272 2645 1.27268 2717 1.27264 2583 1.2726 2752 1.27256 2785 1.27252 2774 1.27248 2821 1.27243 2873 1.27239 2958 1.27235 3111 1.27231 3118 1.27227 3268 1.27223 3382 1.27219 3434 1.27215 3569 1.27211 3691 1.27206 3912 1.27202 3963 1.27198 4254 1.27194 4415 1.2719 4651 1.27186 4858 1.27182 5163 1.27178 5388 1.27174 5820 1.2717 6062 1.27165 6273 1.27161 6553 1.27157 6656 1.27153 7112 1.27149 7350 1.27145 7430 1.27141 7555 1.27137 7652 1.27133 7653 1.27128 7582 1.27124 7581 1.2712 7383 1.27116 7228 1.27112 7185 1.27108 6767 1.27104 6406 1.271 6082 1.27096 6031 1.27091 5656 1.27087 5328 1.27083 5027 1.27079 4761 1.27075 4552 1.27071 4308 1.27067 4080 1.27063 3928 1.27059 3682 1.27054 3555 1.2705 3412 1.27046 3267 1.27042 3271 1.27038 3103 1.27034 2937 1.2703 2823 1.27026 2712 1.27022 2679 1.27018 2616 1.27013 2513 1.27009 2573 1.27005 2420 1.27001 2370 1.26997 2352 1.26993 2297 1.26989 2326 1.26985 2345 1.26981 2220 1.26976 2192 1.26972 2147 1.26968 2156 1.26964 2136 1.2696 2116 1.26956 2095 1.26952 2022 1.26948 2005 1.26944 2083 1.26939 2083 1.26935 2040 1.26931 1970 1.26927 1990 1.26923 1899 1.26919 1914 1.26915 1933 1.26911 1940 1.26907 1940 1.26902 2008 1.26898 1874 1.26894 1975 1.2689 1911 1.26886 1834 1.26882 1791 1.26878 1890 1.26874 1893 1.2687 1766 1.26866 1891 1.26861 1835 1.26857 1918 1.26853 1797 1.26849 1837 1.26845 1846 1.26841 1866 1.26837 1852 1.26833 1933 1.26829 1721 1.26824 1778 1.2682 1777 1.26816 1797 1.26812 1811 1.26808 1756 1.26804 1795 1.268 1771 1.26796 1783 1.26792 1776 1.26787 1728 1.26783 1794 1.26779 1736 1.26775 1801 1.26771 1756 1.26767 1835 1.26763 1775 1.26759 1789 1.26755 1775 1.2675 1742 1.26746 1747 1.26742 1771 1.26738 1791 1.26734 1777 1.2673 1697 1.26726 1737 1.26722 1810 1.26718 1682 1.26714 1770 1.26709 1791 1.26705 1741 1.26701 1661 1.26697 1713 1.26693 1710 1.26689 1752 1.26685 1719 1.26681 1779 1.26677 1750 1.26672 1768 1.26668 1779 1.26664 1766 1.2666 1763 1.26656 1785 1.26652 1793 1.26648 1765 1.26644 1759 1.2664 1722 1.26635 1764 1.26631 1797 1.26627 1795 1.26623 1690 1.26619 1734 1.26615 1790 1.26611 1661 1.26607 1757 1.26603 1744 1.26598 1788 1.26594 1795 1.2659 1702 1.26586 1678 1.26582 1646 1.26578 C 1s/4 PNB300 2015 10 14 12 46 18 0 13 Casa Info Follows 1 Calib M = 280.738 A = 284.6 BE ADD 0 1 CASA region (*C 1s*) (*Shirley*) 1194.084 1207.6589 0.278 2 0 0 299 542 275 9.3 (*C 1s*) 12.011 0 2 CASA comp (*C 1s*) (*GL(30)*) Area 302.12654 0.001 10000000 -1 1 MFWHM 1.8266943 0.38 9.5 -1 1 Position 1202.101 1182.828 1212.828 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) CASA comp (*C 1s*) (*GL(30)*) Area 171.54444 0.001 10000000 -1 1 MFWHM 4.2737578 0.40175352 10.043838 -1 1 Position 1199.1888 1182.828 1212.828 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) pnb300.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 782 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 260 Charge Neutraliser :On Acquired On :15/10/14 12:46:18 XPS 63 0 1 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 C 1s -1 Kinetic Energy eV 1186.69 0.1 2 Intensity d Transmission d pulse counting 0.2597 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 602 664 1184 1.23374 1.24606 755 1.24606 703 1.24602 727 1.24598 732 1.24594 772 1.2459 762 1.24586 712 1.24581 691 1.24577 724 1.24573 692 1.24569 768 1.24565 740 1.24561 724 1.24557 737 1.24553 733 1.24549 705 1.24544 719 1.2454 797 1.24536 740 1.24532 748 1.24528 730 1.24524 705 1.2452 717 1.24516 737 1.24512 768 1.24507 709 1.24503 684 1.24499 735 1.24495 682 1.24491 731 1.24487 706 1.24483 729 1.24479 750 1.24475 769 1.24471 741 1.24466 748 1.24462 704 1.24458 749 1.24454 692 1.2445 705 1.24446 725 1.24442 747 1.24438 706 1.24434 720 1.24429 684 1.24425 708 1.24421 732 1.24417 709 1.24413 725 1.24409 739 1.24405 717 1.24401 697 1.24397 731 1.24392 738 1.24388 745 1.24384 726 1.2438 721 1.24376 743 1.24372 711 1.24368 727 1.24364 715 1.2436 729 1.24355 750 1.24351 753 1.24347 718 1.24343 692 1.24339 719 1.24335 698 1.24331 701 1.24327 719 1.24323 687 1.24319 707 1.24314 728 1.2431 763 1.24306 734 1.24302 698 1.24298 704 1.24294 757 1.2429 727 1.24286 744 1.24282 736 1.24277 728 1.24273 774 1.24269 725 1.24265 731 1.24261 720 1.24257 699 1.24253 749 1.24249 732 1.24245 734 1.2424 707 1.24236 698 1.24232 776 1.24228 733 1.24224 731 1.2422 735 1.24216 715 1.24212 720 1.24208 711 1.24203 730 1.24199 745 1.24195 767 1.24191 691 1.24187 708 1.24183 715 1.24179 759 1.24175 736 1.24171 748 1.24167 741 1.24162 753 1.24158 750 1.24154 724 1.2415 731 1.24146 731 1.24142 691 1.24138 743 1.24134 731 1.2413 681 1.24125 759 1.24121 743 1.24117 704 1.24113 750 1.24109 745 1.24105 720 1.24101 814 1.24097 747 1.24093 706 1.24088 706 1.24084 721 1.2408 709 1.24076 753 1.24072 684 1.24068 717 1.24064 745 1.2406 728 1.24056 732 1.24051 729 1.24047 754 1.24043 712 1.24039 732 1.24035 743 1.24031 719 1.24027 778 1.24023 779 1.24019 806 1.24015 787 1.2401 757 1.24006 785 1.24002 858 1.23998 830 1.23994 862 1.2399 854 1.23986 811 1.23982 796 1.23978 795 1.23973 806 1.23969 880 1.23965 750 1.23961 805 1.23957 820 1.23953 813 1.23949 749 1.23945 843 1.23941 741 1.23936 770 1.23932 798 1.23928 738 1.23924 764 1.2392 790 1.23916 870 1.23912 831 1.23908 892 1.23904 790 1.23899 841 1.23895 852 1.23891 879 1.23887 890 1.23883 899 1.23879 930 1.23875 859 1.23871 880 1.23867 916 1.23863 893 1.23858 946 1.23854 976 1.2385 991 1.23846 1072 1.23842 1033 1.23838 1095 1.23834 1119 1.2383 1107 1.23826 1170 1.23821 1113 1.23817 1172 1.23813 1184 1.23809 1068 1.23805 1128 1.23801 1136 1.23797 1045 1.23793 1035 1.23789 996 1.23784 980 1.2378 941 1.23776 903 1.23772 913 1.23768 820 1.23764 808 1.2376 825 1.23756 766 1.23752 795 1.23747 740 1.23743 819 1.23739 750 1.23735 719 1.23731 710 1.23727 773 1.23723 739 1.23719 729 1.23715 689 1.23711 697 1.23706 701 1.23702 709 1.23698 787 1.23694 759 1.2369 697 1.23686 718 1.23682 721 1.23678 728 1.23674 743 1.23669 730 1.23665 676 1.23661 753 1.23657 737 1.23653 708 1.23649 747 1.23645 734 1.23641 713 1.23637 748 1.23632 738 1.23628 781 1.23624 755 1.2362 772 1.23616 709 1.23612 757 1.23608 691 1.23604 774 1.236 746 1.23595 745 1.23591 753 1.23587 699 1.23583 714 1.23579 772 1.23575 743 1.23571 765 1.23567 751 1.23563 730 1.23559 701 1.23554 705 1.2355 748 1.23546 735 1.23542 766 1.23538 782 1.23534 729 1.2353 742 1.23526 715 1.23522 718 1.23517 718 1.23513 715 1.23509 759 1.23505 728 1.23501 722 1.23497 735 1.23493 743 1.23489 749 1.23485 759 1.2348 729 1.23476 756 1.23472 756 1.23468 756 1.23464 723 1.2346 735 1.23456 743 1.23452 725 1.23448 758 1.23443 700 1.23439 733 1.23435 707 1.23431 781 1.23427 664 1.23423 794 1.23419 777 1.23415 699 1.23411 726 1.23407 741 1.23402 764 1.23398 761 1.23394 721 1.2339 734 1.23386 762 1.23382 760 1.23378 750 1.23374 Nb 3d/5 PNB300 2015 10 14 12 46 18 0 14 Casa Info Follows 1 Calib M = 280.738 A = 284.6 BE ADD 0 1 CASA region (*Nb 3d*) (*Shirley*) 1272.828 1285.828 2.921 2 0 0 299 542 275 9.3 (*Nb 3d*) 92.9064 0 3 CASA comp (*Nb 3d*) (*GL(30)*) Area 2220.5401 0.001 10000000 -1 1 MFWHM 1.1176746 0.26 6.5 -1 1 Position 1279.5162 1272.828 1285.828 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) CASA comp (*Nb 3d*) (*GL(30)*) Area 2026.1498 0.001 10000000 -1 1 MFWHM 1.2119929 0.26 6.5 -1 1 Position 1276.8398 1272.828 1285.828 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) CASA comp (*Nb 3d*) (*GL(30)*) Area 1075.9542 0.001 10000000 -1 1 MFWHM 1.5589815 0.24736016 6.1840039 -1 1 Position 1279.8606 1272.828 1285.828 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) pnb300.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 1200 Sweeps: 20 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 458 Charge Neutraliser :On Acquired On :15/10/14 12:46:18 XPS 63 0 1 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3d -1 Kinetic Energy eV 1276.69 0.1 2 Intensity d Transmission d pulse counting 0.458 20 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 262 519 22960 1.20732 1.2118 2101 1.2118 2131 1.21177 2045 1.21173 2027 1.2117 2051 1.21166 2078 1.21163 2039 1.21159 1987 1.21156 1907 1.21152 1971 1.21149 1896 1.21146 1874 1.21142 1901 1.21139 1791 1.21135 1843 1.21132 1889 1.21128 1849 1.21125 1724 1.21121 1723 1.21118 1778 1.21115 1804 1.21111 1683 1.21108 1701 1.21104 1729 1.21101 1939 1.21097 1988 1.21094 2230 1.2109 2511 1.21087 2863 1.21084 3360 1.2108 4096 1.21077 4987 1.21073 6099 1.2107 7706 1.21066 9033 1.21063 10751 1.21059 12460 1.21056 13946 1.21053 14851 1.21049 15623 1.21046 15708 1.21042 15533 1.21039 14658 1.21035 13331 1.21032 12217 1.21029 10606 1.21025 9155 1.21022 7443 1.21018 6278 1.21015 5295 1.21011 4380 1.21008 3636 1.21004 3334 1.21001 3037 1.20998 3018 1.20994 3329 1.20991 3806 1.20987 4551 1.20984 5834 1.2098 7272 1.20977 9213 1.20973 11389 1.2097 13908 1.20967 16605 1.20963 18871 1.2096 20772 1.20956 22317 1.20953 22960 1.20949 22741 1.20946 21641 1.20942 20034 1.20939 18202 1.20936 15817 1.20932 13534 1.20929 11375 1.20925 9267 1.20922 7558 1.20918 6131 1.20915 4831 1.20911 3957 1.20908 3196 1.20905 2571 1.20901 2132 1.20898 1750 1.20894 1493 1.20891 1250 1.20887 1087 1.20884 1012 1.2088 880 1.20877 787 1.20874 681 1.2087 676 1.20867 710 1.20863 616 1.2086 664 1.20856 633 1.20853 655 1.20849 653 1.20846 629 1.20843 556 1.20839 624 1.20836 561 1.20832 580 1.20829 624 1.20825 603 1.20822 611 1.20819 586 1.20815 525 1.20812 560 1.20808 519 1.20805 565 1.20801 572 1.20798 562 1.20794 571 1.20791 546 1.20788 568 1.20784 557 1.20781 585 1.20777 593 1.20774 614 1.2077 573 1.20767 539 1.20763 559 1.2076 532 1.20757 580 1.20753 556 1.2075 533 1.20746 590 1.20743 557 1.20739 570 1.20736 576 1.20732 Si 2p/6 PNB300 2015 10 14 12 46 18 0 10 Casa Info Follows 1 Calib M = 280.738 A = 284.6 BE ADD 0 0 0 pnb300.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 799 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 397 Charge Neutraliser :On Acquired On :15/10/14 12:46:18 XPS 63 0 1 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Si 2p -1 Kinetic Energy eV 1376.69 0.1 2 Intensity d Transmission d pulse counting 0.3974 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 238 335 1.19156 1.19218 299 1.19218 315 1.19218 265 1.19217 249 1.19217 295 1.19217 257 1.19216 258 1.19216 272 1.19216 273 1.19215 256 1.19215 271 1.19215 302 1.19214 250 1.19214 256 1.19214 254 1.19213 291 1.19213 274 1.19213 259 1.19213 280 1.19212 285 1.19212 317 1.19212 272 1.19211 286 1.19211 287 1.19211 280 1.1921 269 1.1921 299 1.1921 301 1.19209 277 1.19209 266 1.19209 291 1.19209 275 1.19208 269 1.19208 247 1.19208 250 1.19207 267 1.19207 276 1.19207 275 1.19206 250 1.19206 269 1.19206 281 1.19205 278 1.19205 283 1.19205 303 1.19205 248 1.19204 292 1.19204 275 1.19204 293 1.19203 238 1.19203 279 1.19203 303 1.19202 292 1.19202 280 1.19202 305 1.19201 288 1.19201 273 1.19201 294 1.19201 309 1.192 282 1.192 280 1.192 309 1.19199 283 1.19199 312 1.19199 281 1.19198 277 1.19198 280 1.19198 262 1.19197 269 1.19197 280 1.19197 264 1.19196 266 1.19196 263 1.19196 323 1.19196 290 1.19195 286 1.19195 319 1.19195 292 1.19194 287 1.19194 309 1.19194 306 1.19193 307 1.19193 296 1.19193 313 1.19192 245 1.19192 279 1.19192 302 1.19192 292 1.19191 299 1.19191 263 1.19191 289 1.1919 258 1.1919 293 1.1919 306 1.19189 264 1.19189 309 1.19189 298 1.19188 296 1.19188 282 1.19188 286 1.19188 300 1.19187 299 1.19187 275 1.19187 292 1.19186 283 1.19186 280 1.19186 321 1.19185 305 1.19185 298 1.19185 286 1.19184 309 1.19184 285 1.19184 302 1.19184 297 1.19183 313 1.19183 271 1.19183 301 1.19182 273 1.19182 311 1.19182 290 1.19181 335 1.19181 268 1.19181 265 1.1918 294 1.1918 295 1.1918 309 1.1918 331 1.19179 286 1.19179 268 1.19179 281 1.19178 266 1.19178 271 1.19178 284 1.19177 283 1.19177 297 1.19177 287 1.19176 263 1.19176 303 1.19176 239 1.19176 266 1.19175 278 1.19175 279 1.19175 248 1.19174 269 1.19174 293 1.19174 324 1.19173 277 1.19173 297 1.19173 251 1.19172 321 1.19172 286 1.19172 295 1.19171 271 1.19171 274 1.19171 257 1.19171 282 1.1917 268 1.1917 278 1.1917 273 1.19169 253 1.19169 285 1.19169 262 1.19168 263 1.19168 308 1.19168 310 1.19167 290 1.19167 298 1.19167 279 1.19167 286 1.19166 298 1.19166 268 1.19166 270 1.19165 302 1.19165 284 1.19165 287 1.19164 318 1.19164 276 1.19164 321 1.19163 264 1.19163 277 1.19163 255 1.19163 279 1.19162 275 1.19162 285 1.19162 305 1.19161 282 1.19161 289 1.19161 275 1.1916 320 1.1916 313 1.1916 292 1.19159 279 1.19159 261 1.19159 291 1.19159 254 1.19158 284 1.19158 284 1.19158 292 1.19157 269 1.19157 315 1.19157 263 1.19156 284 1.19156 wide/1 PNB500 2015 10 14 15 31 40 0 10 Casa Info Follows 1 Calib M = 283.043 A = 284.6 BE ADD 0 0 0 pnb500.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 160 Acqn. Time(s): 603 Sweeps: 5 Anode:Mono(Al (Mono))(156 W) Step(meV): 1000.0 Dwell Time(ms): 100 Charge Neutraliser :On Acquired On :15/10/14 15:31:40 XPS 63 9 2 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 160 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Wide None -1 Kinetic Energy eV 286.69 1 2 Intensity d Transmission d pulse counting 0.1 5 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 2412 1 1333 4.41569 8.42235 300 8.42235 322 8.38839 301 8.35442 321 8.32045 327 8.28649 313 8.25252 320 8.21856 303 8.18459 324 8.15063 308 8.11666 320 8.0827 310 8.04873 273 8.01476 322 7.9808 318 7.94683 329 7.91287 311 7.8789 313 7.84494 299 7.81097 278 7.77701 298 7.74304 278 7.70907 276 7.67511 266 7.64114 306 7.60718 338 7.57321 319 7.53925 288 7.50528 293 7.47131 309 7.43735 339 7.40338 318 7.36942 310 7.33545 323 7.30149 297 7.26752 310 7.23356 294 7.19959 280 7.16562 292 7.13166 298 7.09769 307 7.06373 296 7.02976 326 7.00512 350 6.99202 312 6.97893 301 6.96583 317 6.95273 295 6.93963 286 6.92653 301 6.91343 301 6.90033 282 6.88723 327 6.87414 295 6.86104 312 6.84794 324 6.83484 302 6.82174 309 6.80864 323 6.79554 302 6.78244 320 6.76935 296 6.75625 274 6.74315 315 6.73005 325 6.71695 278 6.70385 288 6.69075 290 6.67765 340 6.66456 304 6.65146 321 6.63836 316 6.62526 332 6.61216 325 6.59906 298 6.58596 296 6.57286 316 6.55976 290 6.54667 329 6.53357 301 6.52047 310 6.50737 335 6.49427 300 6.48117 323 6.46807 309 6.45497 339 6.44188 339 6.42878 308 6.41568 336 6.40258 301 6.38948 326 6.37638 328 6.36328 347 6.35018 341 6.33709 353 6.32399 351 6.31089 310 6.29779 332 6.28469 321 6.27159 331 6.25849 330 6.24539 338 6.2323 287 6.2192 322 6.2061 354 6.193 336 6.1799 336 6.1668 319 6.1537 323 6.1406 344 6.1275 330 6.11441 313 6.10131 327 6.08821 304 6.07511 333 6.06201 311 6.04891 320 6.03581 312 6.02271 330 6.00962 343 5.99652 330 5.98342 323 5.97032 330 5.95722 330 5.94412 323 5.93102 354 5.91792 323 5.90483 324 5.89173 347 5.87863 360 5.86553 343 5.85243 353 5.83933 329 5.82623 367 5.81313 366 5.80004 362 5.78694 355 5.77384 351 5.76074 355 5.74764 351 5.73454 319 5.72144 342 5.70834 324 5.69524 338 5.68215 343 5.66905 353 5.65595 339 5.64285 311 5.62975 349 5.61665 356 5.60355 346 5.59045 361 5.57736 388 5.56426 360 5.55116 360 5.53806 373 5.52496 363 5.51186 346 5.49876 336 5.48566 339 5.47257 380 5.45947 366 5.44637 366 5.43327 387 5.42017 357 5.40707 340 5.39397 343 5.38087 364 5.36778 369 5.35468 370 5.34158 352 5.33457 405 5.33071 363 5.32684 346 5.32297 381 5.31911 385 5.31524 367 5.31137 354 5.30751 339 5.30364 368 5.29978 353 5.29591 371 5.29204 386 5.28818 372 5.28431 372 5.28044 382 5.27658 388 5.27271 378 5.26885 348 5.26498 372 5.26111 366 5.25725 379 5.25338 359 5.24951 378 5.24565 394 5.24178 378 5.23792 389 5.23405 386 5.23018 367 5.22632 381 5.22245 415 5.21858 397 5.21472 394 5.21085 387 5.20699 398 5.20312 389 5.19925 400 5.19539 367 5.19152 411 5.18765 433 5.18379 405 5.17992 400 5.17606 401 5.17219 394 5.16832 386 5.16446 379 5.16059 381 5.15672 343 5.15286 400 5.14899 353 5.14513 383 5.14126 357 5.13739 381 5.13353 375 5.12966 396 5.12579 430 5.12193 460 5.11806 506 5.1142 472 5.11033 454 5.10646 449 5.1026 407 5.09873 329 5.09486 376 5.091 351 5.08713 341 5.08327 331 5.0794 323 5.07553 282 5.07167 291 5.0678 321 5.06393 293 5.06007 307 5.0562 277 5.05234 281 5.04847 314 5.0446 299 5.04074 292 5.03687 273 5.033 278 5.02914 286 5.02527 274 5.02141 296 5.01754 314 5.01367 302 5.00981 289 5.00594 314 5.00207 253 4.99821 302 4.99434 308 4.99048 307 4.98661 305 4.98274 317 4.97888 300 4.97501 315 4.97114 312 4.96728 295 4.96341 323 4.95955 351 4.95568 278 4.95181 301 4.94795 306 4.94408 325 4.94021 314 4.93635 307 4.93248 309 4.92862 293 4.92475 279 4.92088 301 4.91702 302 4.91315 276 4.90928 271 4.90542 315 4.90155 313 4.89769 293 4.89382 314 4.88995 319 4.88609 309 4.88222 312 4.87835 319 4.87449 316 4.87062 331 4.86676 319 4.86289 313 4.85902 336 4.85516 309 4.85129 328 4.84742 305 4.84356 339 4.83969 332 4.83582 321 4.83196 318 4.82809 316 4.82423 325 4.82036 341 4.81649 296 4.81263 316 4.80876 312 4.80489 327 4.80103 322 4.79716 294 4.7933 304 4.78943 306 4.78556 317 4.7817 297 4.77783 325 4.77396 313 4.7701 321 4.76623 332 4.76237 352 4.7585 331 4.75463 325 4.75077 314 4.7469 318 4.74303 331 4.73917 293 4.7353 331 4.73144 321 4.72757 330 4.7237 329 4.71984 317 4.71597 327 4.7121 313 4.70824 324 4.70437 334 4.70051 322 4.69664 332 4.69277 325 4.68891 314 4.68504 323 4.68117 311 4.67731 337 4.67344 317 4.66958 322 4.66571 314 4.66184 310 4.65798 325 4.65411 344 4.65024 296 4.64638 317 4.64251 303 4.63865 313 4.63478 330 4.63091 310 4.62705 317 4.62318 299 4.61931 341 4.61545 328 4.61158 320 4.60772 315 4.60385 338 4.59998 326 4.59612 332 4.59225 327 4.58838 342 4.58452 348 4.58065 317 4.57679 311 4.57292 314 4.56905 354 4.56519 346 4.56132 309 4.55745 300 4.55359 328 4.54972 341 4.54586 326 4.54199 326 4.53812 326 4.53426 338 4.53039 369 4.52906 350 4.52854 355 4.52803 354 4.52752 324 4.52701 312 4.52649 340 4.52598 320 4.52547 353 4.52495 338 4.52444 364 4.52393 354 4.52341 334 4.5229 344 4.52239 335 4.52188 327 4.52136 351 4.52085 348 4.52034 344 4.51982 378 4.51931 306 4.5188 362 4.51828 340 4.51777 342 4.51726 361 4.51675 356 4.51623 336 4.51572 366 4.51521 358 4.51469 364 4.51418 354 4.51367 361 4.51315 354 4.51264 369 4.51213 349 4.51162 355 4.5111 379 4.51059 360 4.51008 337 4.50956 351 4.50905 362 4.50854 338 4.50803 367 4.50751 348 4.507 338 4.50649 366 4.50597 362 4.50546 364 4.50495 354 4.50443 351 4.50392 347 4.50341 345 4.50289 347 4.50238 336 4.50187 363 4.50136 323 4.50084 363 4.50033 380 4.49982 381 4.4993 365 4.49879 351 4.49828 364 4.49777 375 4.49725 365 4.49674 372 4.49623 347 4.49571 366 4.4952 350 4.49469 371 4.49417 345 4.49366 383 4.49315 378 4.49264 372 4.49212 388 4.49161 378 4.4911 334 4.49058 383 4.49007 386 4.48956 359 4.48904 381 4.48853 350 4.48802 353 4.48751 363 4.48699 392 4.48648 392 4.48597 399 4.48545 374 4.48494 393 4.48443 376 4.48391 363 4.4834 385 4.48289 387 4.48238 373 4.48186 384 4.48135 380 4.48084 361 4.48032 383 4.47981 379 4.4793 396 4.47878 399 4.47827 415 4.47776 378 4.47725 378 4.47673 374 4.47622 392 4.47571 403 4.47519 377 4.47468 365 4.47417 366 4.47365 386 4.47314 420 4.47263 417 4.47212 392 4.4716 384 4.47109 398 4.47058 392 4.47006 385 4.46955 420 4.46904 375 4.46852 380 4.46801 355 4.4675 387 4.46699 383 4.46647 405 4.46596 398 4.46545 366 4.46493 377 4.46442 377 4.46391 367 4.46339 367 4.46288 379 4.46237 386 4.46186 379 4.46134 390 4.46083 374 4.46032 396 4.4598 375 4.45929 389 4.45878 408 4.45826 401 4.45775 360 4.45724 386 4.45673 432 4.45621 378 4.4557 391 4.45519 333 4.45467 367 4.45416 397 4.45365 408 4.45313 432 4.45262 382 4.45211 387 4.4516 421 4.45108 412 4.45057 431 4.45006 428 4.44954 417 4.44903 417 4.44852 411 4.448 422 4.44749 427 4.44698 401 4.44647 397 4.44595 386 4.44544 432 4.44493 396 4.44441 411 4.4439 408 4.44339 430 4.44287 412 4.44236 419 4.44185 405 4.44134 426 4.44082 425 4.44031 409 4.4398 409 4.43928 400 4.43877 396 4.43826 432 4.43775 408 4.43723 461 4.43672 412 4.43621 427 4.43569 447 4.43518 436 4.43467 414 4.43415 437 4.43364 461 4.43313 446 4.43262 430 4.4321 429 4.43159 417 4.43108 400 4.43056 443 4.43005 415 4.42954 423 4.42902 452 4.42851 477 4.428 432 4.42748 411 4.42697 464 4.42646 476 4.42595 446 4.42543 463 4.42492 456 4.42441 397 4.42389 454 4.42338 452 4.42287 445 4.42236 449 4.42184 474 4.42133 448 4.42082 426 4.4203 459 4.41979 420 4.41928 455 4.41876 462 4.41825 462 4.41774 456 4.41723 461 4.41671 487 4.4162 495 4.41569 493 4.41652 464 4.41746 429 4.41841 474 4.41936 457 4.4203 446 4.42125 474 4.4222 435 4.42315 414 4.42409 439 4.42504 449 4.42599 478 4.42694 463 4.42788 490 4.42883 468 4.42978 470 4.43073 450 4.43167 456 4.43262 462 4.43357 463 4.43451 488 4.43546 504 4.43641 456 4.43736 474 4.4383 510 4.43925 479 4.4402 470 4.44115 493 4.44209 499 4.44304 494 4.44399 510 4.44494 477 4.44588 465 4.44683 460 4.44778 486 4.44873 476 4.44967 473 4.45062 529 4.45157 474 4.45251 508 4.45346 490 4.45441 516 4.45536 490 4.4563 495 4.45725 473 4.4582 481 4.45915 510 4.46009 480 4.46104 497 4.46199 515 4.46294 475 4.46388 491 4.46483 500 4.46578 508 4.46672 509 4.46767 458 4.46862 504 4.46957 490 4.47051 494 4.47146 511 4.47241 495 4.47336 474 4.4743 442 4.47525 406 4.4762 414 4.47715 434 4.47809 441 4.47904 433 4.47999 457 4.48094 554 4.48188 757 4.48283 1103 4.48378 1333 4.48472 1000 4.48567 524 4.48662 406 4.48757 366 4.48851 389 4.48946 363 4.49041 353 4.49136 362 4.4923 388 4.49325 397 4.4942 362 4.49515 371 4.49609 357 4.49704 370 4.49799 364 4.49893 377 4.49988 387 4.50083 370 4.50178 372 4.50272 372 4.50367 388 4.50462 388 4.50557 373 4.50651 401 4.50746 351 4.50841 378 4.50936 372 4.5103 390 4.51125 374 4.5122 393 4.51314 385 4.51409 374 4.51504 415 4.51599 371 4.51693 397 4.51788 364 4.51883 390 4.51978 367 4.52072 420 4.52167 417 4.52262 387 4.52357 393 4.52451 405 4.52546 414 4.52641 402 4.52736 400 4.5283 390 4.52925 388 4.5302 411 4.53114 404 4.53209 410 4.53304 400 4.53399 411 4.53493 386 4.53588 384 4.53683 412 4.53778 453 4.53872 470 4.53967 465 4.54062 433 4.54157 427 4.54251 412 4.54346 417 4.54441 402 4.54535 340 4.5463 392 4.54725 344 4.5482 382 4.54914 389 4.55009 378 4.55104 379 4.55199 400 4.55293 374 4.55388 383 4.55483 376 4.55578 399 4.55764 407 4.5599 378 4.56217 365 4.56443 372 4.56669 378 4.56896 366 4.57122 381 4.57349 360 4.57575 405 4.57801 427 4.58028 390 4.58254 381 4.58481 371 4.58707 385 4.58933 358 4.5916 391 4.59386 390 4.59613 395 4.59839 375 4.60065 361 4.60292 382 4.60518 369 4.60745 359 4.60971 395 4.61197 425 4.61424 384 4.6165 383 4.61877 366 4.62103 411 4.62329 414 4.62556 389 4.62782 387 4.63009 391 4.63235 361 4.63461 393 4.63688 407 4.63914 374 4.64141 421 4.64367 428 4.64593 438 4.6482 408 4.65046 444 4.65273 453 4.65499 408 4.65725 406 4.65952 408 4.66178 404 4.66405 432 4.66631 418 4.66857 435 4.67084 381 4.6731 400 4.67537 453 4.67763 408 4.67989 426 4.68216 420 4.68442 461 4.68669 430 4.68895 429 4.69121 394 4.69348 412 4.69574 442 4.69801 441 4.70027 384 4.70253 423 4.7048 412 4.70706 419 4.70933 433 4.71159 438 4.71385 456 4.71612 494 4.71838 599 4.72065 718 4.72291 707 4.72517 578 4.72744 471 4.7297 398 4.73197 351 4.73423 345 4.73649 374 4.73876 354 4.74102 342 4.74329 348 4.74555 325 4.74781 385 4.75008 452 4.75234 608 4.75461 823 4.75687 804 4.75913 695 4.7614 512 4.76366 405 4.76593 319 4.76819 295 4.77045 294 4.77272 264 4.77498 247 4.77725 276 4.77951 259 4.78177 246 4.78404 238 4.7863 246 4.78857 236 4.79083 253 4.79309 248 4.79536 258 4.79762 248 4.79989 285 4.80215 258 4.80441 252 4.80668 230 4.80894 230 4.81121 228 4.81347 268 4.81573 279 4.818 296 4.82026 253 4.82253 233 4.82479 256 4.82705 266 4.82932 240 4.83158 261 4.83385 260 4.83611 257 4.83837 260 4.84064 249 4.8429 250 4.84517 249 4.84743 255 4.84969 253 4.85196 251 4.85422 234 4.85648 251 4.85875 255 4.86101 260 4.86328 294 4.86554 280 4.86781 282 4.87007 267 4.87233 252 4.8746 269 4.87686 261 4.87913 286 4.88139 262 4.88365 265 4.88592 285 4.88818 273 4.89044 273 4.89271 263 4.89497 291 4.89724 298 4.8995 266 4.90176 263 4.90403 288 4.90629 255 4.90856 255 4.91082 267 4.91308 287 4.91535 284 4.91761 295 4.91988 270 4.92214 267 4.9244 266 4.92667 289 4.92893 343 4.9312 341 4.93346 353 4.93572 354 4.93799 390 4.94025 390 4.94252 298 4.94478 307 4.94704 280 4.94931 275 4.95157 275 4.95384 290 4.9561 275 4.95836 263 4.96063 272 4.96289 282 4.96516 280 4.96742 302 4.96968 303 4.97195 285 4.97421 261 4.97648 261 4.97874 274 4.981 266 4.98327 288 4.98553 304 4.9878 304 4.99006 256 4.99232 299 4.99459 290 4.99685 288 4.99912 276 5.00138 298 5.00364 304 5.00591 320 5.00817 295 5.01044 306 5.01342 276 5.01665 255 5.01988 289 5.02311 290 5.02633 307 5.02956 293 5.03279 284 5.03601 288 5.03924 282 5.04247 279 5.0457 257 5.04892 280 5.05215 274 5.05538 263 5.05861 296 5.06183 298 5.06506 322 5.06829 323 5.07152 302 5.07474 313 5.07797 303 5.0812 317 5.08442 351 5.08765 299 5.09088 306 5.09411 334 5.09733 314 5.10056 334 5.10379 369 5.10702 359 5.11024 335 5.11347 356 5.1167 347 5.11993 252 5.12315 255 5.12638 236 5.12961 226 5.13283 232 5.13606 230 5.13929 217 5.14252 254 5.14574 572 5.14897 894 5.1522 904 5.15543 1048 5.15865 1248 5.16188 815 5.16511 255 5.16834 103 5.17156 95 5.17479 82 5.17802 77 5.18124 63 5.18447 78 5.1877 76 5.19093 74 5.19415 73 5.19738 79 5.20061 74 5.20384 72 5.20706 62 5.21029 58 5.21352 70 5.21675 79 5.21997 66 5.2232 79 5.22643 76 5.22965 76 5.23288 77 5.23611 70 5.23934 84 5.24256 87 5.24579 78 5.24902 77 5.25225 79 5.25547 58 5.2587 72 5.26193 78 5.26516 73 5.26838 72 5.27161 69 5.27484 70 5.27806 72 5.28129 82 5.28452 75 5.28775 75 5.29097 78 5.2942 68 5.29743 84 5.30066 90 5.30388 67 5.30711 73 5.31034 80 5.31381 82 5.31803 90 5.32226 72 5.32648 77 5.33071 81 5.33493 90 5.33916 91 5.34338 83 5.34761 74 5.35183 82 5.35606 76 5.36028 75 5.36451 83 5.36873 76 5.37296 76 5.37718 80 5.38141 90 5.38564 69 5.38986 73 5.39409 67 5.39831 88 5.40254 65 5.40676 74 5.41099 74 5.41521 75 5.41944 73 5.42366 61 5.42789 69 5.43211 79 5.43634 79 5.44056 83 5.44479 85 5.44902 82 5.45324 82 5.45747 89 5.46169 74 5.46592 75 5.47014 85 5.47437 79 5.47859 66 5.48282 76 5.48704 71 5.49127 80 5.49549 69 5.49972 80 5.50394 101 5.50817 88 5.5124 88 5.51662 79 5.52085 74 5.52507 85 5.5293 65 5.53352 73 5.53775 88 5.54197 88 5.5462 79 5.55042 94 5.55465 100 5.55887 86 5.5631 89 5.56732 82 5.57155 84 5.57578 83 5.58 85 5.58423 87 5.58845 93 5.59268 90 5.5969 69 5.60113 79 5.60535 77 5.60958 80 5.6138 90 5.61803 88 5.62225 72 5.62648 72 5.6307 79 5.63493 86 5.63916 96 5.64338 88 5.64761 96 5.65183 85 5.65606 79 5.66028 77 5.66451 73 5.66873 70 5.67296 94 5.67718 91 5.68141 76 5.68563 87 5.68986 85 5.69408 96 5.69831 79 5.70254 72 5.70676 78 5.71099 98 5.71521 94 5.71944 120 5.72366 113 5.72789 124 5.73211 126 5.73634 103 5.74056 75 5.74479 89 5.74901 80 5.75324 68 5.75746 82 5.76169 76 5.76591 93 5.77014 75 5.77437 71 5.77859 70 5.78282 81 5.78704 76 5.79127 66 5.79549 58 5.79972 70 5.80394 70 5.80817 57 5.81239 69 5.81662 69 5.82084 78 5.82507 135 5.8293 151 5.83352 185 5.83775 225 5.84197 160 5.8462 87 5.85042 49 5.85465 27 5.85887 35 5.8631 35 5.86732 35 5.87155 35 5.87577 41 5.87603 37 5.87603 54 5.87603 66 5.87603 68 5.87603 72 5.87603 51 5.87603 35 5.87603 33 5.87603 22 5.87603 12 5.87603 20 5.87603 10 5.87603 19 5.87603 17 5.87603 7 5.87603 12 5.87603 21 5.87603 37 5.87603 58 5.87603 62 5.87603 44 5.87603 34 5.87603 19 5.87603 9 5.87603 4 5.87603 2 5.87603 1 5.87603 1 5.87603 O 1s/2 PNB500 2015 10 14 15 51 11 0 13 Casa Info Follows 1 Calib M = 283.043 A = 284.6 BE ADD 0 1 CASA region (*O 1s*) (*Shirley*) 951.12334 961.49371 0.78 2 0 0 299 542 275 9.3 (*O 1s*) 15.9994 0 2 CASA comp (*O 1s*) (*GL(30)*) Area 2559.0499 0.001 10000000 -1 1 MFWHM 1.7254419 0.38 9.5 -1 1 Position 956.70241 945.133 965.133 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) CASA comp (*O 1s*) (*GL(30)*) Area 265.3429 0.001 10000000 -1 1 MFWHM 1.5872828 0.37536446 9.3841115 -1 1 Position 954.72362 945.133 965.133 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) pnb500.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 666 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 332 Charge Neutraliser :On Acquired On :15/10/14 15:51:11 XPS 71 7 2 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 O 1s -1 Kinetic Energy eV 946.69 0.1 2 Intensity d Transmission d pulse counting 0.3315 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 1084 5818 1.31473 1.31659 1485 1.31659 1473 1.31658 1453 1.31657 1487 1.31656 1510 1.31655 1431 1.31654 1435 1.31653 1429 1.31652 1375 1.31651 1435 1.3165 1372 1.3165 1409 1.31649 1456 1.31648 1410 1.31647 1408 1.31646 1292 1.31645 1397 1.31644 1374 1.31643 1367 1.31642 1314 1.31641 1315 1.3164 1352 1.31639 1408 1.31638 1334 1.31637 1268 1.31637 1416 1.31636 1346 1.31635 1429 1.31634 1350 1.31633 1373 1.31632 1385 1.31631 1395 1.3163 1370 1.31629 1336 1.31628 1427 1.31627 1301 1.31626 1391 1.31625 1300 1.31624 1305 1.31623 1359 1.31623 1327 1.31622 1345 1.31621 1375 1.3162 1324 1.31619 1335 1.31618 1300 1.31617 1333 1.31616 1310 1.31615 1350 1.31614 1375 1.31613 1290 1.31612 1354 1.31611 1354 1.3161 1364 1.3161 1312 1.31609 1310 1.31608 1262 1.31607 1274 1.31606 1281 1.31605 1287 1.31604 1267 1.31603 1315 1.31602 1284 1.31601 1332 1.316 1337 1.31599 1241 1.31598 1293 1.31597 1235 1.31597 1285 1.31596 1242 1.31595 1273 1.31594 1273 1.31593 1256 1.31592 1272 1.31591 1239 1.3159 1335 1.31589 1270 1.31588 1306 1.31587 1225 1.31586 1347 1.31585 1371 1.31584 1363 1.31584 1435 1.31583 1387 1.31582 1410 1.31581 1448 1.3158 1473 1.31579 1527 1.31578 1492 1.31577 1648 1.31576 1561 1.31575 1801 1.31574 1699 1.31573 1859 1.31572 1862 1.31571 1901 1.3157 1924 1.3157 2002 1.31569 2172 1.31568 2147 1.31567 2294 1.31566 2317 1.31565 2430 1.31564 2732 1.31563 2795 1.31562 3035 1.31561 3339 1.3156 3588 1.31559 4028 1.31558 4302 1.31557 4551 1.31557 4944 1.31556 5286 1.31555 5321 1.31554 5790 1.31553 5818 1.31552 5813 1.31551 5739 1.3155 5546 1.31549 5242 1.31548 4946 1.31547 4545 1.31546 4261 1.31545 3925 1.31544 3552 1.31544 3118 1.31543 2840 1.31542 2550 1.31541 2271 1.3154 2125 1.31539 2040 1.31538 1736 1.31537 1642 1.31536 1602 1.31535 1521 1.31534 1444 1.31533 1406 1.31532 1399 1.31531 1318 1.31531 1246 1.3153 1210 1.31529 1240 1.31528 1245 1.31527 1188 1.31526 1264 1.31525 1173 1.31524 1136 1.31523 1205 1.31522 1171 1.31521 1186 1.3152 1142 1.31519 1141 1.31518 1146 1.31517 1120 1.31517 1171 1.31516 1128 1.31515 1132 1.31514 1154 1.31513 1141 1.31512 1153 1.31511 1102 1.3151 1216 1.31509 1176 1.31508 1101 1.31507 1178 1.31506 1174 1.31505 1103 1.31504 1156 1.31504 1137 1.31503 1095 1.31502 1085 1.31501 1103 1.315 1113 1.31499 1199 1.31498 1145 1.31497 1183 1.31496 1084 1.31495 1134 1.31494 1176 1.31493 1096 1.31492 1193 1.31491 1140 1.31491 1147 1.3149 1141 1.31489 1140 1.31488 1105 1.31487 1153 1.31486 1104 1.31485 1216 1.31484 1129 1.31483 1097 1.31482 1151 1.31481 1167 1.3148 1155 1.31479 1143 1.31478 1120 1.31478 1162 1.31477 1116 1.31476 1148 1.31475 1190 1.31474 1228 1.31473 Nb 3p/3 PNB500 2015 10 14 15 51 11 0 15 Casa Info Follows 1 Calib M = 283.043 A = 284.6 BE ADD 0 1 CASA region (*Nb 3p*) (*Shirley*) 1098.2842 1129.3391 2.63 2 0 0 299 542 275 9.3 (*Nb 3p*) 92.9064 0 4 CASA comp (*Nb 3p*) (*GL(30)*) Area 1376.9891 0.001 10000000 -1 1 MFWHM 2.2857809 0.54 13.5 -1 1 Position 1120.9689 1093.133 1137.133 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 652.0546 0.001 10000000 -1 1 MFWHM 2.133232 0.54 13.5 -1 1 Position 1105.4841 1093.133 1137.133 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 856.60885 0.001 10000000 -1 1 MFWHM 4.5713266 0.59260531 14.815133 -1 1 Position 1121.9487 1093.133 1137.133 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 721.63055 0.001 10000000 -1 1 MFWHM 4.5148174 0.66162349 16.540587 -1 1 Position 1106.399 1093.133 1137.133 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) pnb500.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 2871 Sweeps: 50 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 130 Charge Neutraliser :On Acquired On :15/10/14 15:51:11 XPS 71 7 2 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3p -1 Kinetic Energy eV 1094.69 0.1 2 Intensity d Transmission d pulse counting 0.1302 50 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 882 1463 6628 1.26578 1.28386 2657 1.28386 2637 1.28381 2699 1.28377 2673 1.28373 2668 1.28369 2693 1.28365 2665 1.28361 2695 1.28357 2685 1.28353 2633 1.28349 2588 1.28344 2614 1.2834 2622 1.28336 2675 1.28332 2594 1.28328 2571 1.28324 2671 1.2832 2594 1.28316 2615 1.28312 2583 1.28307 2636 1.28303 2560 1.28299 2625 1.28295 2566 1.28291 2564 1.28287 2639 1.28283 2618 1.28279 2597 1.28275 2550 1.2827 2537 1.28266 2635 1.28262 2623 1.28258 2539 1.28254 2603 1.2825 2566 1.28246 2666 1.28242 2469 1.28238 2492 1.28234 2600 1.28229 2691 1.28225 2651 1.28221 2631 1.28217 2492 1.28213 2475 1.28209 2627 1.28205 2607 1.28201 2623 1.28197 2509 1.28192 2642 1.28188 2703 1.28184 2611 1.2818 2511 1.28176 2545 1.28172 2664 1.28168 2654 1.28164 2554 1.2816 2603 1.28155 2548 1.28151 2551 1.28147 2614 1.28143 2550 1.28139 2595 1.28135 2554 1.28131 2561 1.28127 2620 1.28123 2481 1.28118 2529 1.28114 2471 1.2811 2506 1.28106 2515 1.28102 2543 1.28098 2577 1.28094 2545 1.2809 2601 1.28086 2590 1.28082 2527 1.28077 2508 1.28073 2519 1.28069 2551 1.28065 2650 1.28061 2564 1.28057 2628 1.28053 2582 1.28049 2567 1.28045 2677 1.2804 2648 1.28036 2675 1.28032 2597 1.28028 2787 1.28024 2667 1.2802 2639 1.28016 2636 1.28012 2693 1.28008 2659 1.28003 2668 1.27999 2752 1.27995 2813 1.27991 2794 1.27987 2813 1.27983 2828 1.27979 2962 1.27975 2890 1.27971 2992 1.27966 3022 1.27962 3117 1.27958 3183 1.27954 3270 1.2795 3386 1.27946 3350 1.27942 3503 1.27938 3610 1.27934 3701 1.2793 3810 1.27925 4136 1.27921 4034 1.27917 4180 1.27913 4377 1.27909 4678 1.27905 4665 1.27901 4889 1.27897 4969 1.27893 5039 1.27888 5123 1.27884 5142 1.2788 5145 1.27876 4996 1.27872 5065 1.27868 5013 1.27864 4828 1.2786 4704 1.27856 4655 1.27851 4536 1.27847 4553 1.27843 4295 1.27839 4283 1.27835 4120 1.27831 4074 1.27827 3911 1.27823 3695 1.27819 3563 1.27814 3642 1.2781 3381 1.27806 3324 1.27802 3357 1.27798 3246 1.27794 3222 1.2779 3071 1.27786 3091 1.27782 2982 1.27778 2904 1.27773 2974 1.27769 2817 1.27765 2756 1.27761 2840 1.27757 2740 1.27753 2706 1.27749 2623 1.27745 2650 1.27741 2659 1.27736 2685 1.27732 2552 1.27728 2603 1.27724 2523 1.2772 2429 1.27716 2580 1.27712 2424 1.27708 2430 1.27704 2383 1.27699 2311 1.27695 2430 1.27691 2381 1.27687 2389 1.27683 2375 1.27679 2227 1.27675 2369 1.27671 2333 1.27667 2419 1.27662 2344 1.27658 2347 1.27654 2281 1.2765 2193 1.27646 2257 1.27642 2279 1.27638 2333 1.27634 2181 1.2763 2264 1.27626 2168 1.27621 2250 1.27617 2221 1.27613 2226 1.27609 2245 1.27605 2234 1.27601 2207 1.27597 2179 1.27593 2184 1.27589 2216 1.27584 2169 1.2758 2265 1.27576 2201 1.27572 2202 1.27568 2216 1.27564 2195 1.2756 2243 1.27556 2226 1.27552 2312 1.27547 2102 1.27543 2210 1.27539 2168 1.27535 2237 1.27531 2251 1.27527 2170 1.27523 2155 1.27519 2207 1.27515 2249 1.2751 2207 1.27506 2183 1.27502 2175 1.27498 2223 1.27494 2203 1.2749 2136 1.27486 2125 1.27482 2050 1.27478 2221 1.27474 2150 1.27469 2140 1.27465 2124 1.27461 2202 1.27457 2148 1.27453 2198 1.27449 2189 1.27445 2092 1.27441 2196 1.27437 2133 1.27432 2206 1.27428 2218 1.27424 2195 1.2742 2195 1.27416 2214 1.27412 2211 1.27408 2256 1.27404 2126 1.274 2207 1.27395 2237 1.27391 2299 1.27387 2313 1.27383 2320 1.27379 2399 1.27375 2381 1.27371 2468 1.27367 2426 1.27363 2495 1.27358 2541 1.27354 2571 1.2735 2598 1.27346 2623 1.27342 2835 1.27338 2861 1.27334 2881 1.2733 2939 1.27326 3110 1.27322 3283 1.27317 3347 1.27313 3574 1.27309 3786 1.27305 3814 1.27301 4113 1.27297 4232 1.27293 4564 1.27289 4686 1.27285 4951 1.2728 5249 1.27276 5519 1.27272 5816 1.27268 5954 1.27264 6223 1.2726 6239 1.27256 6489 1.27252 6456 1.27248 6494 1.27243 6562 1.27239 6628 1.27235 6398 1.27231 6399 1.27227 6052 1.27223 5909 1.27219 5722 1.27215 5483 1.27211 5295 1.27206 4999 1.27202 4912 1.27198 4641 1.27194 4458 1.2719 4176 1.27186 4064 1.27182 3843 1.27178 3631 1.27174 3375 1.2717 3449 1.27165 3275 1.27161 3060 1.27157 3096 1.27153 2800 1.27149 2910 1.27145 2670 1.27141 2631 1.27137 2449 1.27133 2394 1.27128 2370 1.27124 2319 1.2712 2268 1.27116 2271 1.27112 2236 1.27108 2145 1.27104 2098 1.271 2066 1.27096 2141 1.27091 1962 1.27087 1982 1.27083 1955 1.27079 1975 1.27075 1930 1.27071 1952 1.27067 1827 1.27063 1883 1.27059 1856 1.27054 1794 1.2705 1855 1.27046 1753 1.27042 1777 1.27038 1765 1.27034 1678 1.2703 1743 1.27026 1765 1.27022 1814 1.27018 1717 1.27013 1754 1.27009 1733 1.27005 1701 1.27001 1718 1.26997 1699 1.26993 1685 1.26989 1645 1.26985 1612 1.26981 1680 1.26976 1708 1.26972 1673 1.26968 1692 1.26964 1587 1.2696 1646 1.26956 1632 1.26952 1667 1.26948 1720 1.26944 1625 1.26939 1652 1.26935 1608 1.26931 1618 1.26927 1672 1.26923 1587 1.26919 1681 1.26915 1607 1.26911 1608 1.26907 1641 1.26902 1571 1.26898 1589 1.26894 1588 1.2689 1670 1.26886 1569 1.26882 1602 1.26878 1698 1.26874 1666 1.2687 1576 1.26866 1638 1.26861 1614 1.26857 1621 1.26853 1566 1.26849 1658 1.26845 1525 1.26841 1596 1.26837 1554 1.26833 1515 1.26829 1528 1.26824 1546 1.2682 1551 1.26816 1576 1.26812 1605 1.26808 1509 1.26804 1526 1.268 1550 1.26796 1613 1.26792 1495 1.26787 1568 1.26783 1586 1.26779 1582 1.26775 1498 1.26771 1554 1.26767 1576 1.26763 1601 1.26759 1523 1.26755 1533 1.2675 1616 1.26746 1600 1.26742 1588 1.26738 1524 1.26734 1533 1.2673 1517 1.26726 1588 1.26722 1582 1.26718 1604 1.26714 1575 1.26709 1585 1.26705 1577 1.26701 1616 1.26697 1604 1.26693 1667 1.26689 1615 1.26685 1463 1.26681 1582 1.26677 1578 1.26672 1577 1.26668 1481 1.26664 1468 1.2666 1546 1.26656 1602 1.26652 1520 1.26648 1568 1.26644 1592 1.2664 1536 1.26635 1486 1.26631 1627 1.26627 1584 1.26623 1590 1.26619 1596 1.26615 1492 1.26611 1579 1.26607 1531 1.26603 1481 1.26598 1589 1.26594 1583 1.2659 1511 1.26586 1583 1.26582 1620 1.26578 C 1s/4 PNB500 2015 10 14 15 51 11 0 14 Casa Info Follows 1 Calib M = 283.043 A = 284.6 Regions BE ADD 0 1 CASA region (*C 1s*) (*Shirley*) 1191.376 1213.1634 0.278 2 0 0 299 542 275 9.3 (*C 1s*) 12.011 0 3 CASA comp (*C 1s*) (*GL(30)*) Area 42.523621 0.001 10000000 -1 1 MFWHM 0.93174282 0.46 11.5 -1 1 Position 1202.2409 1185.133 1215.133 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) CASA comp (*C 1s*) (*GL(30)*) Area 20.070854 0.001 10000000 -1 1 MFWHM 0.88427759 0.7083994 17.709985 -1 1 Position 1197.5963 1185.133 1215.133 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) CASA comp (*C 1s*) (*GL(30)*) Area 339.22098 0.001 10000000 -1 1 MFWHM 3.9256472 2.1184926 52.962316 -1 1 Position 1201.7121 1185.133 1215.133 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) pnb500.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 782 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 260 Charge Neutraliser :On Acquired On :15/10/14 15:51:11 XPS 71 7 2 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 C 1s -1 Kinetic Energy eV 1186.69 0.1 2 Intensity d Transmission d pulse counting 0.2597 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 602 600 985 1.23374 1.24606 656 1.24606 656 1.24602 684 1.24598 640 1.24594 652 1.2459 698 1.24586 710 1.24581 702 1.24577 655 1.24573 635 1.24569 685 1.24565 672 1.24561 676 1.24557 675 1.24553 684 1.24549 651 1.24544 645 1.2454 720 1.24536 677 1.24532 678 1.24528 696 1.24524 632 1.2452 710 1.24516 663 1.24512 655 1.24507 721 1.24503 678 1.24499 673 1.24495 671 1.24491 623 1.24487 620 1.24483 618 1.24479 686 1.24475 691 1.24471 722 1.24466 658 1.24462 677 1.24458 629 1.24454 666 1.2445 674 1.24446 628 1.24442 639 1.24438 639 1.24434 661 1.24429 656 1.24425 647 1.24421 636 1.24417 668 1.24413 658 1.24409 690 1.24405 666 1.24401 657 1.24397 649 1.24392 675 1.24388 669 1.24384 661 1.2438 633 1.24376 669 1.24372 651 1.24368 667 1.24364 664 1.2436 600 1.24355 671 1.24351 677 1.24347 673 1.24343 643 1.24339 663 1.24335 649 1.24331 642 1.24327 665 1.24323 650 1.24319 653 1.24314 651 1.2431 643 1.24306 616 1.24302 630 1.24298 668 1.24294 667 1.2429 684 1.24286 642 1.24282 712 1.24277 656 1.24273 669 1.24269 629 1.24265 672 1.24261 665 1.24257 642 1.24253 671 1.24249 655 1.24245 673 1.2424 612 1.24236 659 1.24232 651 1.24228 636 1.24224 634 1.2422 655 1.24216 681 1.24212 681 1.24208 660 1.24203 656 1.24199 697 1.24195 642 1.24191 690 1.24187 657 1.24183 621 1.24179 712 1.24175 636 1.24171 623 1.24167 682 1.24162 636 1.24158 660 1.24154 669 1.2415 726 1.24146 673 1.24142 668 1.24138 659 1.24134 670 1.2413 664 1.24125 641 1.24121 695 1.24117 673 1.24113 730 1.24109 713 1.24105 692 1.24101 720 1.24097 730 1.24093 721 1.24088 730 1.24084 693 1.2408 721 1.24076 689 1.24072 715 1.24068 716 1.24064 640 1.2406 684 1.24056 730 1.24051 718 1.24047 700 1.24043 698 1.24039 696 1.24035 720 1.24031 731 1.24027 726 1.24023 774 1.24019 704 1.24015 743 1.2401 758 1.24006 768 1.24002 761 1.23998 741 1.23994 781 1.2399 838 1.23986 833 1.23982 838 1.23978 811 1.23973 806 1.23969 866 1.23965 807 1.23961 886 1.23957 877 1.23953 863 1.23949 834 1.23945 890 1.23941 851 1.23936 908 1.23932 892 1.23928 915 1.23924 943 1.2392 925 1.23916 984 1.23912 967 1.23908 985 1.23904 976 1.23899 946 1.23895 885 1.23891 902 1.23887 898 1.23883 885 1.23879 882 1.23875 837 1.23871 808 1.23867 828 1.23863 807 1.23858 747 1.23854 768 1.2385 800 1.23846 685 1.23842 762 1.23838 749 1.23834 741 1.2383 758 1.23826 749 1.23821 731 1.23817 719 1.23813 726 1.23809 697 1.23805 692 1.23801 734 1.23797 729 1.23793 732 1.23789 725 1.23784 680 1.2378 714 1.23776 704 1.23772 712 1.23768 736 1.23764 694 1.2376 674 1.23756 719 1.23752 717 1.23747 686 1.23743 668 1.23739 651 1.23735 625 1.23731 658 1.23727 692 1.23723 656 1.23719 679 1.23715 668 1.23711 646 1.23706 652 1.23702 691 1.23698 704 1.23694 684 1.2369 638 1.23686 687 1.23682 663 1.23678 655 1.23674 642 1.23669 669 1.23665 628 1.23661 678 1.23657 664 1.23653 699 1.23649 632 1.23645 657 1.23641 664 1.23637 618 1.23632 649 1.23628 658 1.23624 651 1.2362 661 1.23616 650 1.23612 628 1.23608 669 1.23604 645 1.236 671 1.23595 703 1.23591 712 1.23587 686 1.23583 653 1.23579 681 1.23575 662 1.23571 664 1.23567 671 1.23563 639 1.23559 664 1.23554 684 1.2355 660 1.23546 670 1.23542 652 1.23538 697 1.23534 668 1.2353 656 1.23526 699 1.23522 659 1.23517 660 1.23513 642 1.23509 613 1.23505 641 1.23501 642 1.23497 710 1.23493 648 1.23489 650 1.23485 636 1.2348 686 1.23476 654 1.23472 610 1.23468 693 1.23464 657 1.2346 695 1.23456 660 1.23452 664 1.23448 692 1.23443 649 1.23439 645 1.23435 667 1.23431 697 1.23427 693 1.23423 658 1.23419 664 1.23415 706 1.23411 657 1.23407 670 1.23402 691 1.23398 696 1.23394 654 1.2339 654 1.23386 643 1.23382 673 1.23378 653 1.23374 Nb 3d/5 PNB500 2015 10 14 15 51 11 0 15 Casa Info Follows 1 Calib M = 283.043 A = 284.6 BE ADD 0 1 CASA region (*Nb 3d*) (*Shirley*) 1275.133 1283.4857 2.921 2 0 0 299 542 275 9.3 (*Nb 3d*) 92.9064 0 4 CASA comp (*Nb 3d*) (*GL(30)*) Area 1853.6836 0.001 10000000 -1 1 MFWHM 1.1328037 0.28 7 -1 1 Position 1279.2898 1275.133 1288.133 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) CASA comp (*Nb 3d*) (*GL(30)*) Area 630.85103 0.001 10000000 -1 1 MFWHM 1.2725213 0.28 7 -1 1 Position 1277.1305 1275.133 1288.133 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) CASA comp (*Nb 3d*) (*GL(30)*) Area 1016.3768 0.001 10000000 -1 1 MFWHM 1.5837929 0.26819764 6.7049409 -1 1 Position 1279.8772 1275.133 1288.133 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) CASA comp (*Nb 3d*) (*GL(30)*) Area 1143.8695 0.001 10000000 -1 1 MFWHM 1.0647458 0.26739979 6.6849947 -1 1 Position 1276.5072 1275.133 1288.133 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) pnb500.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 1200 Sweeps: 20 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 458 Charge Neutraliser :On Acquired On :15/10/14 15:51:11 XPS 71 7 2 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3d -1 Kinetic Energy eV 1276.69 0.1 2 Intensity d Transmission d pulse counting 0.458 20 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 262 568 18616 1.20732 1.2118 1839 1.2118 1922 1.21177 2184 1.21173 2449 1.2117 2854 1.21166 3524 1.21163 4301 1.21159 5265 1.21156 6476 1.21152 7584 1.21149 9035 1.21146 10246 1.21142 11689 1.21139 12241 1.21135 12904 1.21132 13124 1.21128 12842 1.21125 12109 1.21121 11309 1.21118 10226 1.21115 9235 1.21111 8016 1.21108 7211 1.21104 6418 1.21101 5424 1.21097 4839 1.21094 4254 1.2109 3843 1.21087 3519 1.21084 3416 1.2108 3553 1.21077 3733 1.21073 4343 1.2107 5222 1.21066 6350 1.21063 8038 1.21059 9859 1.21056 11822 1.21053 13968 1.21049 15877 1.21046 16988 1.21042 18089 1.21039 18616 1.21035 18560 1.21032 17752 1.21029 16664 1.21025 15417 1.21022 13507 1.21018 11905 1.21015 10173 1.21011 9113 1.21008 7667 1.21004 6662 1.21001 5617 1.20998 4726 1.20994 3914 1.20991 3321 1.20987 2740 1.20984 2343 1.2098 2210 1.20977 1703 1.20973 1447 1.2097 1338 1.20967 1175 1.20963 1056 1.2096 994 1.20956 958 1.20953 946 1.20949 834 1.20946 789 1.20942 758 1.20939 754 1.20936 745 1.20932 899 1.20929 685 1.20925 631 1.20922 657 1.20918 647 1.20915 636 1.20911 675 1.20908 673 1.20905 593 1.20901 641 1.20898 658 1.20894 620 1.20891 651 1.20887 632 1.20884 852 1.2088 568 1.20877 629 1.20874 593 1.2087 616 1.20867 633 1.20863 611 1.2086 591 1.20856 602 1.20853 627 1.20849 626 1.20846 581 1.20843 609 1.20839 610 1.20836 838 1.20832 623 1.20829 628 1.20825 599 1.20822 609 1.20819 649 1.20815 637 1.20812 589 1.20808 664 1.20805 618 1.20801 633 1.20798 607 1.20794 657 1.20791 640 1.20788 643 1.20784 620 1.20781 688 1.20777 615 1.20774 611 1.2077 648 1.20767 625 1.20763 645 1.2076 592 1.20757 616 1.20753 632 1.2075 647 1.20746 633 1.20743 631 1.20739 657 1.20736 646 1.20732 Si 2p/6 PNB500 2015 10 14 15 51 11 0 10 Casa Info Follows 1 Calib M = 283.043 A = 284.6 BE ADD 0 0 0 pnb500.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 799 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 397 Charge Neutraliser :On Acquired On :15/10/14 15:51:11 XPS 71 7 2 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Si 2p -1 Kinetic Energy eV 1376.69 0.1 2 Intensity d Transmission d pulse counting 0.3974 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 247 360 1.19156 1.19218 298 1.19218 301 1.19218 268 1.19217 285 1.19217 304 1.19217 300 1.19216 263 1.19216 311 1.19216 296 1.19215 324 1.19215 282 1.19215 296 1.19214 290 1.19214 286 1.19214 275 1.19213 291 1.19213 305 1.19213 283 1.19213 315 1.19212 304 1.19212 278 1.19212 323 1.19211 279 1.19211 251 1.19211 295 1.1921 291 1.1921 300 1.1921 289 1.19209 295 1.19209 286 1.19209 268 1.19209 313 1.19208 259 1.19208 286 1.19208 289 1.19207 293 1.19207 271 1.19207 275 1.19206 307 1.19206 297 1.19206 271 1.19205 273 1.19205 288 1.19205 288 1.19205 297 1.19204 280 1.19204 282 1.19204 278 1.19203 300 1.19203 282 1.19203 294 1.19202 270 1.19202 272 1.19202 297 1.19201 295 1.19201 260 1.19201 261 1.19201 268 1.192 271 1.192 288 1.192 297 1.19199 274 1.19199 280 1.19199 299 1.19198 287 1.19198 299 1.19198 268 1.19197 308 1.19197 282 1.19197 293 1.19196 296 1.19196 293 1.19196 303 1.19196 290 1.19195 302 1.19195 296 1.19195 313 1.19194 310 1.19194 341 1.19194 318 1.19193 284 1.19193 288 1.19193 306 1.19192 326 1.19192 296 1.19192 314 1.19192 329 1.19191 347 1.19191 319 1.19191 324 1.1919 338 1.1919 345 1.1919 360 1.19189 335 1.19189 339 1.19189 344 1.19188 340 1.19188 321 1.19188 353 1.19188 348 1.19187 333 1.19187 334 1.19187 340 1.19186 341 1.19186 330 1.19186 334 1.19185 333 1.19185 313 1.19185 329 1.19184 311 1.19184 285 1.19184 323 1.19184 332 1.19183 271 1.19183 331 1.19183 345 1.19182 285 1.19182 299 1.19182 288 1.19181 276 1.19181 312 1.19181 276 1.1918 299 1.1918 302 1.1918 289 1.1918 279 1.19179 335 1.19179 270 1.19179 300 1.19178 302 1.19178 288 1.19178 295 1.19177 304 1.19177 300 1.19177 280 1.19176 248 1.19176 273 1.19176 307 1.19176 247 1.19175 252 1.19175 292 1.19175 283 1.19174 294 1.19174 263 1.19174 313 1.19173 287 1.19173 286 1.19173 273 1.19172 268 1.19172 295 1.19172 294 1.19171 275 1.19171 275 1.19171 273 1.19171 264 1.1917 267 1.1917 286 1.1917 283 1.19169 288 1.19169 284 1.19169 292 1.19168 289 1.19168 269 1.19168 293 1.19167 285 1.19167 290 1.19167 255 1.19167 297 1.19166 282 1.19166 271 1.19166 290 1.19165 302 1.19165 290 1.19165 288 1.19164 299 1.19164 297 1.19164 305 1.19163 299 1.19163 266 1.19163 276 1.19163 311 1.19162 293 1.19162 289 1.19162 278 1.19161 313 1.19161 297 1.19161 271 1.1916 315 1.1916 266 1.1916 289 1.19159 314 1.19159 281 1.19159 299 1.19159 318 1.19158 288 1.19158 284 1.19158 254 1.19157 312 1.19157 279 1.19157 293 1.19156 294 1.19156 wide/1 PNB700 2015 10 14 18 36 33 0 10 Casa Info Follows 1 Calib M = 280.725 A = 284.6 BE ADD 0 0 0 pnb700.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 160 Acqn. Time(s): 603 Sweeps: 5 Anode:Mono(Al (Mono))(156 W) Step(meV): 1000.0 Dwell Time(ms): 100 Charge Neutraliser :On Acquired On :15/10/14 18:36:33 XPS 71 2 3 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 160 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Wide None -1 Kinetic Energy eV 286.69 1 2 Intensity d Transmission d pulse counting 0.1 5 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 2412 0 1547 4.41569 8.42235 319 8.42235 305 8.38839 308 8.35442 286 8.32045 283 8.28649 331 8.25252 292 8.21856 309 8.18459 297 8.15063 309 8.11666 302 8.0827 293 8.04873 317 8.01476 305 7.9808 286 7.94683 296 7.91287 295 7.8789 315 7.84494 326 7.81097 330 7.77701 302 7.74304 315 7.70907 328 7.67511 314 7.64114 319 7.60718 303 7.57321 303 7.53925 288 7.50528 330 7.47131 309 7.43735 307 7.40338 295 7.36942 295 7.33545 329 7.30149 297 7.26752 325 7.23356 294 7.19959 289 7.16562 306 7.13166 336 7.09769 320 7.06373 311 7.02976 296 7.00512 258 6.99202 310 6.97893 296 6.96583 322 6.95273 309 6.93963 300 6.92653 300 6.91343 308 6.90033 345 6.88723 307 6.87414 280 6.86104 331 6.84794 300 6.83484 302 6.82174 283 6.80864 311 6.79554 293 6.78244 310 6.76935 304 6.75625 304 6.74315 291 6.73005 316 6.71695 308 6.70385 331 6.69075 334 6.67765 325 6.66456 349 6.65146 282 6.63836 316 6.62526 281 6.61216 312 6.59906 281 6.58596 309 6.57286 302 6.55976 329 6.54667 295 6.53357 312 6.52047 309 6.50737 279 6.49427 325 6.48117 307 6.46807 317 6.45497 329 6.44188 307 6.42878 309 6.41568 327 6.40258 325 6.38948 321 6.37638 315 6.36328 336 6.35018 337 6.33709 314 6.32399 328 6.31089 334 6.29779 353 6.28469 292 6.27159 324 6.25849 339 6.24539 329 6.2323 345 6.2192 318 6.2061 344 6.193 361 6.1799 301 6.1668 344 6.1537 328 6.1406 350 6.1275 325 6.11441 329 6.10131 339 6.08821 343 6.07511 376 6.06201 304 6.04891 323 6.03581 355 6.02271 310 6.00962 361 5.99652 333 5.98342 356 5.97032 359 5.95722 336 5.94412 329 5.93102 327 5.91792 310 5.90483 340 5.89173 341 5.87863 359 5.86553 363 5.85243 323 5.83933 351 5.82623 321 5.81313 313 5.80004 346 5.78694 328 5.77384 331 5.76074 370 5.74764 380 5.73454 346 5.72144 352 5.70834 337 5.69524 359 5.68215 392 5.66905 347 5.65595 368 5.64285 361 5.62975 322 5.61665 341 5.60355 314 5.59045 343 5.57736 344 5.56426 352 5.55116 363 5.53806 367 5.52496 340 5.51186 341 5.49876 363 5.48566 348 5.47257 358 5.45947 344 5.44637 335 5.43327 340 5.42017 382 5.40707 359 5.39397 361 5.38087 364 5.36778 356 5.35468 368 5.34158 380 5.33457 343 5.33071 359 5.32684 379 5.32297 348 5.31911 365 5.31524 363 5.31137 378 5.30751 375 5.30364 361 5.29978 346 5.29591 338 5.29204 367 5.28818 360 5.28431 384 5.28044 395 5.27658 355 5.27271 370 5.26885 407 5.26498 413 5.26111 373 5.25725 400 5.25338 365 5.24951 372 5.24565 395 5.24178 381 5.23792 404 5.23405 399 5.23018 407 5.22632 353 5.22245 379 5.21858 375 5.21472 343 5.21085 355 5.20699 400 5.20312 396 5.19925 387 5.19539 399 5.19152 397 5.18765 444 5.18379 407 5.17992 389 5.17606 391 5.17219 402 5.16832 387 5.16446 380 5.16059 370 5.15672 353 5.15286 368 5.14899 380 5.14513 377 5.14126 372 5.13739 352 5.13353 355 5.12966 385 5.12579 390 5.12193 406 5.11806 445 5.1142 476 5.11033 500 5.10646 514 5.1026 464 5.09873 416 5.09486 394 5.091 360 5.08713 398 5.08327 350 5.0794 347 5.07553 311 5.07167 324 5.0678 307 5.06393 289 5.06007 302 5.0562 283 5.05234 291 5.04847 311 5.0446 257 5.04074 295 5.03687 294 5.033 311 5.02914 324 5.02527 280 5.02141 343 5.01754 282 5.01367 299 5.00981 321 5.00594 283 5.00207 304 4.99821 296 4.99434 281 4.99048 284 4.98661 312 4.98274 290 4.97888 310 4.97501 310 4.97114 328 4.96728 287 4.96341 286 4.95955 305 4.95568 302 4.95181 315 4.94795 329 4.94408 312 4.94021 336 4.93635 271 4.93248 315 4.92862 318 4.92475 315 4.92088 297 4.91702 306 4.91315 300 4.90928 309 4.90542 321 4.90155 283 4.89769 309 4.89382 301 4.88995 307 4.88609 300 4.88222 288 4.87835 333 4.87449 339 4.87062 323 4.86676 328 4.86289 295 4.85902 340 4.85516 324 4.85129 360 4.84742 305 4.84356 339 4.83969 324 4.83582 320 4.83196 305 4.82809 331 4.82423 303 4.82036 317 4.81649 334 4.81263 335 4.80876 313 4.80489 308 4.80103 331 4.79716 310 4.7933 334 4.78943 351 4.78556 325 4.7817 323 4.77783 335 4.77396 332 4.7701 334 4.76623 338 4.76237 314 4.7585 322 4.75463 320 4.75077 326 4.7469 330 4.74303 298 4.73917 331 4.7353 328 4.73144 326 4.72757 349 4.7237 319 4.71984 314 4.71597 357 4.7121 336 4.70824 346 4.70437 367 4.70051 329 4.69664 324 4.69277 332 4.68891 326 4.68504 346 4.68117 355 4.67731 354 4.67344 358 4.66958 348 4.66571 354 4.66184 332 4.65798 348 4.65411 338 4.65024 336 4.64638 315 4.64251 339 4.63865 324 4.63478 356 4.63091 347 4.62705 332 4.62318 327 4.61931 348 4.61545 324 4.61158 330 4.60772 334 4.60385 350 4.59998 340 4.59612 347 4.59225 345 4.58838 326 4.58452 323 4.58065 356 4.57679 353 4.57292 315 4.56905 347 4.56519 375 4.56132 353 4.55745 343 4.55359 361 4.54972 323 4.54586 339 4.54199 374 4.53812 371 4.53426 348 4.53039 332 4.52906 335 4.52854 365 4.52803 346 4.52752 347 4.52701 349 4.52649 365 4.52598 354 4.52547 348 4.52495 382 4.52444 384 4.52393 347 4.52341 394 4.5229 397 4.52239 368 4.52188 356 4.52136 334 4.52085 356 4.52034 361 4.51982 364 4.51931 379 4.5188 358 4.51828 351 4.51777 359 4.51726 339 4.51675 370 4.51623 367 4.51572 418 4.51521 366 4.51469 367 4.51418 364 4.51367 354 4.51315 380 4.51264 393 4.51213 388 4.51162 357 4.5111 368 4.51059 378 4.51008 381 4.50956 411 4.50905 397 4.50854 373 4.50803 361 4.50751 392 4.507 385 4.50649 396 4.50597 415 4.50546 410 4.50495 382 4.50443 374 4.50392 416 4.50341 382 4.50289 397 4.50238 407 4.50187 379 4.50136 345 4.50084 363 4.50033 365 4.49982 384 4.4993 420 4.49879 395 4.49828 429 4.49777 367 4.49725 371 4.49674 362 4.49623 403 4.49571 402 4.4952 396 4.49469 422 4.49417 429 4.49366 405 4.49315 366 4.49264 400 4.49212 402 4.49161 414 4.4911 408 4.49058 418 4.49007 430 4.48956 422 4.48904 391 4.48853 397 4.48802 392 4.48751 401 4.48699 417 4.48648 419 4.48597 433 4.48545 392 4.48494 427 4.48443 376 4.48391 375 4.4834 398 4.48289 385 4.48238 428 4.48186 407 4.48135 387 4.48084 387 4.48032 456 4.47981 417 4.4793 397 4.47878 459 4.47827 398 4.47776 406 4.47725 409 4.47673 415 4.47622 439 4.47571 422 4.47519 425 4.47468 443 4.47417 446 4.47365 396 4.47314 448 4.47263 463 4.47212 449 4.4716 464 4.47109 473 4.47058 443 4.47006 440 4.46955 453 4.46904 445 4.46852 416 4.46801 458 4.4675 445 4.46699 418 4.46647 445 4.46596 431 4.46545 431 4.46493 471 4.46442 452 4.46391 467 4.46339 441 4.46288 431 4.46237 428 4.46186 457 4.46134 455 4.46083 461 4.46032 406 4.4598 471 4.45929 430 4.45878 437 4.45826 460 4.45775 451 4.45724 423 4.45673 470 4.45621 455 4.4557 465 4.45519 433 4.45467 461 4.45416 483 4.45365 436 4.45313 461 4.45262 492 4.45211 460 4.4516 462 4.45108 439 4.45057 425 4.45006 457 4.44954 447 4.44903 458 4.44852 458 4.448 456 4.44749 437 4.44698 463 4.44647 514 4.44595 480 4.44544 467 4.44493 476 4.44441 470 4.4439 459 4.44339 438 4.44287 458 4.44236 507 4.44185 464 4.44134 465 4.44082 519 4.44031 496 4.4398 471 4.43928 491 4.43877 473 4.43826 466 4.43775 489 4.43723 478 4.43672 472 4.43621 471 4.43569 537 4.43518 499 4.43467 461 4.43415 494 4.43364 484 4.43313 497 4.43262 506 4.4321 478 4.43159 498 4.43108 496 4.43056 488 4.43005 493 4.42954 492 4.42902 495 4.42851 519 4.428 529 4.42748 483 4.42697 501 4.42646 510 4.42595 495 4.42543 481 4.42492 476 4.42441 477 4.42389 520 4.42338 489 4.42287 499 4.42236 507 4.42184 514 4.42133 498 4.42082 539 4.4203 539 4.41979 500 4.41928 526 4.41876 475 4.41825 501 4.41774 525 4.41723 511 4.41671 542 4.4162 549 4.41569 531 4.41652 526 4.41746 545 4.41841 534 4.41936 541 4.4203 504 4.42125 541 4.4222 532 4.42315 518 4.42409 523 4.42504 524 4.42599 549 4.42694 564 4.42788 567 4.42883 511 4.42978 548 4.43073 580 4.43167 556 4.43262 538 4.43357 538 4.43451 553 4.43546 574 4.43641 555 4.43736 537 4.4383 547 4.43925 581 4.4402 567 4.44115 566 4.44209 570 4.44304 574 4.44399 566 4.44494 556 4.44588 581 4.44683 534 4.44778 525 4.44873 574 4.44967 552 4.45062 554 4.45157 548 4.45251 579 4.45346 569 4.45441 554 4.45536 587 4.4563 577 4.45725 574 4.4582 569 4.45915 584 4.46009 560 4.46104 537 4.46199 570 4.46294 588 4.46388 567 4.46483 577 4.46578 586 4.46672 611 4.46767 581 4.46862 576 4.46957 562 4.47051 613 4.47146 539 4.47241 573 4.47336 525 4.4743 486 4.47525 488 4.4762 511 4.47715 473 4.47809 495 4.47904 487 4.47999 515 4.48094 574 4.48188 588 4.48283 766 4.48378 1247 4.48472 1475 4.48567 1190 4.48662 625 4.48757 467 4.48851 436 4.48946 405 4.49041 431 4.49136 429 4.4923 418 4.49325 442 4.4942 422 4.49515 466 4.49609 466 4.49704 445 4.49799 399 4.49893 384 4.49988 435 4.50083 436 4.50178 431 4.50272 440 4.50367 432 4.50462 427 4.50557 425 4.50651 471 4.50746 425 4.50841 453 4.50936 422 4.5103 444 4.51125 454 4.5122 477 4.51314 449 4.51409 456 4.51504 464 4.51599 458 4.51693 463 4.51788 454 4.51883 455 4.51978 488 4.52072 454 4.52167 442 4.52262 443 4.52357 453 4.52451 498 4.52546 461 4.52641 461 4.52736 459 4.5283 442 4.52925 482 4.5302 486 4.53114 498 4.53209 452 4.53304 442 4.53399 467 4.53493 478 4.53588 446 4.53683 467 4.53778 509 4.53872 507 4.53967 527 4.54062 553 4.54157 548 4.54251 566 4.54346 501 4.54441 530 4.54535 477 4.5463 441 4.54725 465 4.5482 469 4.54914 489 4.55009 453 4.55104 438 4.55199 454 4.55293 459 4.55388 428 4.55483 434 4.55578 442 4.55764 470 4.5599 455 4.56217 459 4.56443 447 4.56669 436 4.56896 435 4.57122 443 4.57349 485 4.57575 480 4.57801 479 4.58028 450 4.58254 460 4.58481 460 4.58707 463 4.58933 451 4.5916 430 4.59386 462 4.59613 451 4.59839 457 4.60065 440 4.60292 445 4.60518 480 4.60745 460 4.60971 430 4.61197 494 4.61424 462 4.6165 450 4.61877 474 4.62103 462 4.62329 483 4.62556 491 4.62782 475 4.63009 475 4.63235 478 4.63461 471 4.63688 464 4.63914 485 4.64141 440 4.64367 465 4.64593 481 4.6482 510 4.65046 460 4.65273 497 4.65499 474 4.65725 510 4.65952 503 4.66178 517 4.66405 464 4.66631 478 4.66857 494 4.67084 481 4.6731 459 4.67537 493 4.67763 471 4.67989 473 4.68216 503 4.68442 513 4.68669 489 4.68895 511 4.69121 462 4.69348 506 4.69574 490 4.69801 513 4.70027 518 4.70253 495 4.7048 496 4.70706 464 4.70933 459 4.71159 448 4.71385 476 4.71612 528 4.71838 565 4.72065 756 4.72291 862 4.72517 856 4.72744 668 4.7297 553 4.73197 460 4.73423 428 4.73649 378 4.73876 422 4.74102 387 4.74329 391 4.74555 410 4.74781 391 4.75008 452 4.75234 500 4.75461 714 4.75687 947 4.75913 1094 4.7614 871 4.76366 573 4.76593 458 4.76819 347 4.77045 324 4.77272 316 4.77498 306 4.77725 301 4.77951 308 4.78177 297 4.78404 268 4.7863 295 4.78857 304 4.79083 298 4.79309 272 4.79536 303 4.79762 288 4.79989 331 4.80215 292 4.80441 279 4.80668 317 4.80894 313 4.81121 310 4.81347 277 4.81573 268 4.818 323 4.82026 308 4.82253 322 4.82479 280 4.82705 313 4.82932 290 4.83158 293 4.83385 300 4.83611 298 4.83837 325 4.84064 290 4.8429 307 4.84517 312 4.84743 305 4.84969 294 4.85196 339 4.85422 321 4.85648 292 4.85875 308 4.86101 298 4.86328 313 4.86554 302 4.86781 303 4.87007 294 4.87233 321 4.8746 302 4.87686 295 4.87913 299 4.88139 327 4.88365 312 4.88592 319 4.88818 308 4.89044 331 4.89271 327 4.89497 323 4.89724 328 4.8995 320 4.90176 328 4.90403 328 4.90629 313 4.90856 329 4.91082 325 4.91308 325 4.91535 331 4.91761 307 4.91988 312 4.92214 288 4.9244 298 4.92667 297 4.92893 314 4.9312 332 4.93346 341 4.93572 363 4.93799 416 4.94025 465 4.94252 453 4.94478 343 4.94704 319 4.94931 317 4.95157 325 4.95384 344 4.9561 352 4.95836 331 4.96063 322 4.96289 321 4.96516 329 4.96742 321 4.96968 343 4.97195 324 4.97421 337 4.97648 311 4.97874 301 4.981 331 4.98327 312 4.98553 321 4.9878 303 4.99006 332 4.99232 329 4.99459 312 4.99685 317 4.99912 319 5.00138 334 5.00364 338 5.00591 362 5.00817 372 5.01044 343 5.01342 375 5.01665 363 5.01988 356 5.02311 332 5.02633 356 5.02956 353 5.03279 341 5.03601 335 5.03924 322 5.04247 350 5.0457 323 5.04892 335 5.05215 322 5.05538 350 5.05861 351 5.06183 375 5.06506 362 5.06829 390 5.07152 365 5.07474 377 5.07797 381 5.0812 344 5.08442 350 5.08765 403 5.09088 353 5.09411 351 5.09733 352 5.10056 389 5.10379 434 5.10702 441 5.11024 406 5.11347 422 5.1167 421 5.11993 410 5.12315 305 5.12638 282 5.12961 294 5.13283 282 5.13606 244 5.13929 222 5.14252 210 5.14574 257 5.14897 610 5.1522 1133 5.15543 1109 5.15865 1168 5.16188 1547 5.16511 1028 5.16834 308 5.17156 90 5.17479 81 5.17802 85 5.18124 85 5.18447 79 5.1877 65 5.19093 67 5.19415 77 5.19738 84 5.20061 77 5.20384 80 5.20706 90 5.21029 79 5.21352 66 5.21675 78 5.21997 71 5.2232 82 5.22643 76 5.22965 84 5.23288 74 5.23611 63 5.23934 62 5.24256 95 5.24579 70 5.24902 80 5.25225 67 5.25547 65 5.2587 73 5.26193 67 5.26516 57 5.26838 71 5.27161 59 5.27484 73 5.27806 78 5.28129 88 5.28452 87 5.28775 79 5.29097 74 5.2942 66 5.29743 70 5.30066 78 5.30388 79 5.30711 74 5.31034 80 5.31381 91 5.31803 95 5.32226 79 5.32648 80 5.33071 85 5.33493 79 5.33916 90 5.34338 77 5.34761 73 5.35183 81 5.35606 77 5.36028 77 5.36451 81 5.36873 77 5.37296 78 5.37718 88 5.38141 78 5.38564 89 5.38986 87 5.39409 77 5.39831 80 5.40254 74 5.40676 75 5.41099 74 5.41521 82 5.41944 83 5.42366 87 5.42789 91 5.43211 85 5.43634 77 5.44056 83 5.44479 85 5.44902 73 5.45324 80 5.45747 89 5.46169 88 5.46592 85 5.47014 99 5.47437 75 5.47859 91 5.48282 81 5.48704 77 5.49127 85 5.49549 98 5.49972 97 5.50394 85 5.50817 99 5.5124 81 5.51662 97 5.52085 100 5.52507 86 5.5293 80 5.53352 85 5.53775 100 5.54197 94 5.5462 92 5.55042 94 5.55465 104 5.55887 84 5.5631 84 5.56732 82 5.57155 93 5.57578 99 5.58 96 5.58423 86 5.58845 89 5.59268 90 5.5969 94 5.60113 94 5.60535 76 5.60958 92 5.6138 106 5.61803 92 5.62225 82 5.62648 92 5.6307 101 5.63493 95 5.63916 98 5.64338 101 5.64761 103 5.65183 112 5.65606 92 5.66028 103 5.66451 91 5.66873 89 5.67296 92 5.67718 95 5.68141 93 5.68563 83 5.68986 83 5.69408 79 5.69831 100 5.70254 84 5.70676 77 5.71099 89 5.71521 98 5.71944 97 5.72366 96 5.72789 114 5.73211 128 5.73634 117 5.74056 113 5.74479 116 5.74901 98 5.75324 89 5.75746 75 5.76169 93 5.76591 87 5.77014 94 5.77437 86 5.77859 95 5.78282 81 5.78704 84 5.79127 67 5.79549 67 5.79972 71 5.80394 68 5.80817 68 5.81239 69 5.81662 73 5.82084 95 5.82507 96 5.8293 154 5.83352 183 5.83775 305 5.84197 266 5.8462 207 5.85042 95 5.85465 52 5.85887 42 5.8631 29 5.86732 32 5.87155 41 5.87577 39 5.87603 31 5.87603 49 5.87603 47 5.87603 73 5.87603 92 5.87603 99 5.87603 59 5.87603 43 5.87603 29 5.87603 24 5.87603 19 5.87603 11 5.87603 11 5.87603 14 5.87603 9 5.87603 10 5.87603 15 5.87603 20 5.87603 33 5.87603 56 5.87603 57 5.87603 44 5.87603 35 5.87603 21 5.87603 10 5.87603 2 5.87603 0 5.87603 1 5.87603 O 1s/2 PNB700 2015 10 14 18 56 4 0 13 Casa Info Follows 1 Calib M = 280.725 A = 284.6 BE ADD 0 1 CASA region (*O 1s*) (*Shirley*) 953.57184 960.81822 0.78 2 0 0 299 542 275 9.3 (*O 1s*) 15.9994 0 2 CASA comp (*O 1s*) (*GL(30)*) Area 2503.7345 0.001 10000000 -1 1 MFWHM 1.2142092 0.26 6.5 -1 1 Position 956.85413 942.815 962.815 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) CASA comp (*O 1s*) (*GL(30)*) Area 186.19429 0.001 10000000 -1 1 MFWHM 1.8043869 0.25270831 6.3177078 -1 1 Position 955.53657 942.815 962.815 -1 1 RSF 0.78 MASS 15.9994 INDEX -1 (*O 1s*) CONST (**) pnb700.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 666 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 332 Charge Neutraliser :On Acquired On :15/10/14 18:56:04 XPS 79 1 3 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 O 1s -1 Kinetic Energy eV 946.69 0.1 2 Intensity d Transmission d pulse counting 0.3315 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 1266 7930 1.31473 1.31659 1895 1.31659 1866 1.31658 1806 1.31657 1779 1.31656 1791 1.31655 1822 1.31654 1758 1.31653 1785 1.31652 1723 1.31651 1762 1.3165 1797 1.3165 1752 1.31649 1713 1.31648 1806 1.31647 1791 1.31646 1793 1.31645 1699 1.31644 1741 1.31643 1672 1.31642 1762 1.31641 1676 1.3164 1629 1.31639 1695 1.31638 1727 1.31637 1553 1.31637 1618 1.31636 1567 1.31635 1653 1.31634 1671 1.31633 1654 1.31632 1590 1.31631 1553 1.3163 1519 1.31629 1599 1.31628 1566 1.31627 1616 1.31626 1581 1.31625 1616 1.31624 1555 1.31623 1562 1.31623 1564 1.31622 1614 1.31621 1580 1.3162 1449 1.31619 1507 1.31618 1508 1.31617 1562 1.31616 1484 1.31615 1541 1.31614 1493 1.31613 1568 1.31612 1548 1.31611 1493 1.3161 1530 1.3161 1497 1.31609 1513 1.31608 1516 1.31607 1508 1.31606 1553 1.31605 1493 1.31604 1531 1.31603 1463 1.31602 1557 1.31601 1538 1.316 1564 1.31599 1499 1.31598 1500 1.31597 1564 1.31597 1572 1.31596 1575 1.31595 1448 1.31594 1472 1.31593 1508 1.31592 1509 1.31591 1496 1.3159 1491 1.31589 1516 1.31588 1475 1.31587 1550 1.31586 1531 1.31585 1553 1.31584 1489 1.31584 1469 1.31583 1463 1.31582 1512 1.31581 1469 1.3158 1536 1.31579 1528 1.31578 1488 1.31577 1565 1.31576 1514 1.31575 1538 1.31574 1539 1.31573 1537 1.31572 1530 1.31571 1541 1.3157 1635 1.3157 1600 1.31569 1601 1.31568 1677 1.31567 1628 1.31566 1621 1.31565 1651 1.31564 1608 1.31563 1690 1.31562 1762 1.31561 1667 1.3156 1691 1.31559 1705 1.31558 1739 1.31557 1755 1.31557 1764 1.31556 1705 1.31555 1781 1.31554 1715 1.31553 1755 1.31552 1832 1.31551 1855 1.3155 1936 1.31549 1865 1.31548 2027 1.31547 1921 1.31546 1948 1.31545 2070 1.31544 2073 1.31544 2098 1.31543 2227 1.31542 2269 1.31541 2393 1.3154 2637 1.31539 2939 1.31538 3258 1.31537 3646 1.31536 4289 1.31535 4798 1.31534 5499 1.31533 6162 1.31532 6675 1.31531 7187 1.31531 7800 1.3153 7930 1.31529 7771 1.31528 7434 1.31527 7029 1.31526 6379 1.31525 5655 1.31524 4954 1.31523 4143 1.31522 3527 1.31521 2976 1.3152 2489 1.31519 2111 1.31518 2013 1.31517 1761 1.31517 1580 1.31516 1598 1.31515 1461 1.31514 1379 1.31513 1405 1.31512 1355 1.31511 1320 1.3151 1335 1.31509 1346 1.31508 1382 1.31507 1357 1.31506 1338 1.31505 1321 1.31504 1281 1.31504 1391 1.31503 1305 1.31502 1347 1.31501 1281 1.315 1322 1.31499 1365 1.31498 1319 1.31497 1361 1.31496 1416 1.31495 1366 1.31494 1331 1.31493 1332 1.31492 1297 1.31491 1365 1.31491 1303 1.3149 1285 1.31489 1294 1.31488 1318 1.31487 1283 1.31486 1316 1.31485 1298 1.31484 1328 1.31483 1300 1.31482 1266 1.31481 1312 1.3148 1275 1.31479 1332 1.31478 1283 1.31478 1270 1.31477 1351 1.31476 1270 1.31475 1291 1.31474 1347 1.31473 Nb 3p/3 PNB700 2015 10 14 18 56 4 0 15 Casa Info Follows 1 Calib M = 280.725 A = 284.6 BE ADD 0 1 CASA region (*Nb 3p*) (*Shirley*) 1100.2385 1131.4849 2.63 2 0 0 299 542 275 9.3 (*Nb 3p*) 92.9064 0 4 CASA comp (*Nb 3p*) (*GL(30)*) Area 1544.8389 0.001 10000000 -1 1 MFWHM 2.0471761 0.48 12 -1 1 Position 1121.5783 1090.815 1134.815 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 1353.7992 0.001 10000000 -1 1 MFWHM 2.5175004 0.48 12 -1 1 Position 1106.136 1090.815 1134.815 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 1021.7052 0.001 10000000 -1 1 MFWHM 4.6849159 0.54626454 13.656613 -1 1 Position 1122.2145 1090.815 1134.815 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) CASA comp (*Nb 3p*) (*GL(30)*) Area 235.08732 0.001 10000000 -1 1 MFWHM 3.1978367 0.63980423 15.995106 -1 1 Position 1108.8898 1090.815 1134.815 -1 1 RSF 2.63 MASS 92.9064 INDEX -1 (*Nb 3p*) CONST (**) pnb700.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 2871 Sweeps: 50 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 130 Charge Neutraliser :On Acquired On :15/10/14 18:56:04 XPS 79 1 3 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3p -1 Kinetic Energy eV 1094.69 0.1 2 Intensity d Transmission d pulse counting 0.1302 50 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 882 1660 8038 1.26578 1.28386 3095 1.28386 3092 1.28381 3067 1.28377 3049 1.28373 3209 1.28369 3093 1.28365 3133 1.28361 3160 1.28357 3189 1.28353 3126 1.28349 3115 1.28344 3210 1.2834 3082 1.28336 3114 1.28332 3146 1.28328 3059 1.28324 3124 1.2832 3072 1.28316 3130 1.28312 3107 1.28307 3037 1.28303 3097 1.28299 3104 1.28295 3110 1.28291 3013 1.28287 3000 1.28283 3054 1.28279 3045 1.28275 3039 1.2827 3036 1.28266 3114 1.28262 3032 1.28258 3034 1.28254 3071 1.2825 2989 1.28246 3094 1.28242 3036 1.28238 3025 1.28234 2843 1.28229 2904 1.28225 3045 1.28221 3049 1.28217 2946 1.28213 2989 1.28209 2984 1.28205 3033 1.28201 3081 1.28197 2900 1.28192 2887 1.28188 2947 1.28184 2969 1.2818 2970 1.28176 2915 1.28172 3010 1.28168 2911 1.28164 2960 1.2816 2961 1.28155 2971 1.28151 2878 1.28147 2922 1.28143 2892 1.28139 2954 1.28135 2919 1.28131 2936 1.28127 2986 1.28123 2918 1.28118 2885 1.28114 2956 1.2811 2907 1.28106 2910 1.28102 2968 1.28098 2888 1.28094 2973 1.2809 2938 1.28086 2977 1.28082 2892 1.28077 2907 1.28073 2912 1.28069 2947 1.28065 2949 1.28061 2955 1.28057 2883 1.28053 2965 1.28049 3030 1.28045 3039 1.2804 2848 1.28036 2979 1.28032 2991 1.28028 2844 1.28024 2853 1.2802 2893 1.28016 2908 1.28012 2793 1.28008 2945 1.28003 2756 1.27999 2834 1.27995 2929 1.27991 2964 1.27987 2896 1.27983 2907 1.27979 2877 1.27975 2988 1.27971 2995 1.27966 2849 1.27962 2860 1.27958 2986 1.27954 2874 1.2795 2889 1.27946 2898 1.27942 2891 1.27938 2840 1.27934 3020 1.2793 2996 1.27925 2892 1.27921 2963 1.27917 2945 1.27913 2908 1.27909 2952 1.27905 2963 1.27901 3080 1.27897 3078 1.27893 2997 1.27888 3247 1.27884 3098 1.2788 3025 1.27876 3117 1.27872 3183 1.27868 3149 1.27864 3302 1.2786 3308 1.27856 3251 1.27851 3287 1.27847 3272 1.27843 3380 1.27839 3541 1.27835 3585 1.27831 3704 1.27827 3855 1.27823 3943 1.27819 4029 1.27814 4231 1.2781 4415 1.27806 4562 1.27802 4693 1.27798 5016 1.27794 4953 1.2779 5223 1.27786 5407 1.27782 5677 1.27778 5829 1.27773 5909 1.27769 5930 1.27765 6043 1.27761 5997 1.27757 5933 1.27753 5931 1.27749 6023 1.27745 5727 1.27741 5472 1.27736 5524 1.27732 5448 1.27728 5064 1.27724 4802 1.2772 4884 1.27716 4634 1.27712 4422 1.27708 4385 1.27704 4139 1.27699 3998 1.27695 3974 1.27691 3825 1.27687 3665 1.27683 3478 1.27679 3499 1.27675 3456 1.27671 3395 1.27667 3406 1.27662 3294 1.27658 3198 1.27654 3130 1.2765 3144 1.27646 3044 1.27642 3150 1.27638 2962 1.27634 2945 1.2763 2882 1.27626 2876 1.27621 2870 1.27617 2840 1.27613 2773 1.27609 2826 1.27605 2763 1.27601 2773 1.27597 2685 1.27593 2706 1.27589 2661 1.27584 2765 1.2758 2610 1.27576 2655 1.27572 2698 1.27568 2684 1.27564 2632 1.2756 2559 1.27556 2523 1.27552 2626 1.27547 2487 1.27543 2621 1.27539 2572 1.27535 2505 1.27531 2472 1.27527 2426 1.27523 2468 1.27519 2433 1.27515 2432 1.2751 2477 1.27506 2515 1.27502 2423 1.27498 2516 1.27494 2450 1.2749 2408 1.27486 2445 1.27482 2519 1.27478 2447 1.27474 2477 1.27469 2510 1.27465 2457 1.27461 2419 1.27457 2482 1.27453 2501 1.27449 2474 1.27445 2414 1.27441 2359 1.27437 2448 1.27432 2424 1.27428 2426 1.27424 2401 1.2742 2415 1.27416 2356 1.27412 2541 1.27408 2407 1.27404 2404 1.274 2421 1.27395 2396 1.27391 2354 1.27387 2351 1.27383 2428 1.27379 2485 1.27375 2399 1.27371 2423 1.27367 2373 1.27363 2404 1.27358 2401 1.27354 2491 1.2735 2389 1.27346 2404 1.27342 2375 1.27338 2444 1.27334 2362 1.2733 2399 1.27326 2460 1.27322 2378 1.27317 2444 1.27313 2445 1.27309 2505 1.27305 2368 1.27301 2427 1.27297 2540 1.27293 2426 1.27289 2458 1.27285 2419 1.2728 2581 1.27276 2528 1.27272 2540 1.27268 2578 1.27264 2569 1.2726 2670 1.27256 2668 1.27252 2719 1.27248 2624 1.27243 2695 1.27239 2789 1.27235 2841 1.27231 2906 1.27227 3022 1.27223 3038 1.27219 3111 1.27215 3222 1.27211 3295 1.27206 3395 1.27202 3616 1.27198 3769 1.27194 3958 1.2719 4162 1.27186 4447 1.27182 4585 1.27178 4728 1.27174 5111 1.2717 5261 1.27165 5614 1.27161 6022 1.27157 6237 1.27153 6512 1.27149 6871 1.27145 7358 1.27141 7507 1.27137 7787 1.27133 7809 1.27128 7918 1.27124 8038 1.2712 7881 1.27116 7771 1.27112 7645 1.27108 7300 1.27104 6924 1.271 6813 1.27096 6376 1.27091 6144 1.27087 5683 1.27083 5442 1.27079 5088 1.27075 4912 1.27071 4638 1.27067 4320 1.27063 4048 1.27059 3866 1.27054 3660 1.2705 3479 1.27046 3400 1.27042 3241 1.27038 3208 1.27034 3070 1.2703 2980 1.27026 2821 1.27022 2831 1.27018 2627 1.27013 2618 1.27009 2618 1.27005 2452 1.27001 2489 1.26997 2450 1.26993 2399 1.26989 2301 1.26985 2347 1.26981 2248 1.26976 2225 1.26972 2290 1.26968 2252 1.26964 2143 1.2696 2150 1.26956 2159 1.26952 2034 1.26948 2054 1.26944 2015 1.26939 1977 1.26935 1994 1.26931 1965 1.26927 1983 1.26923 2050 1.26919 2024 1.26915 1948 1.26911 1949 1.26907 1913 1.26902 1887 1.26898 1960 1.26894 2047 1.2689 1973 1.26886 1930 1.26882 1808 1.26878 1880 1.26874 1887 1.2687 1891 1.26866 1858 1.26861 1922 1.26857 1925 1.26853 1793 1.26849 1867 1.26845 1837 1.26841 1863 1.26837 1822 1.26833 1876 1.26829 1851 1.26824 1816 1.2682 1804 1.26816 1826 1.26812 1821 1.26808 1755 1.26804 1749 1.268 1725 1.26796 1808 1.26792 1788 1.26787 1826 1.26783 1764 1.26779 1882 1.26775 1740 1.26771 1781 1.26767 1836 1.26763 1679 1.26759 1789 1.26755 1711 1.2675 1789 1.26746 1823 1.26742 1789 1.26738 1772 1.26734 1782 1.2673 1759 1.26726 1783 1.26722 1774 1.26718 1830 1.26714 1780 1.26709 1760 1.26705 1778 1.26701 1761 1.26697 1660 1.26693 1745 1.26689 1753 1.26685 1715 1.26681 1756 1.26677 1804 1.26672 1758 1.26668 1747 1.26664 1811 1.2666 1877 1.26656 1700 1.26652 1720 1.26648 1751 1.26644 1746 1.2664 1724 1.26635 1804 1.26631 1750 1.26627 1738 1.26623 1762 1.26619 1752 1.26615 1710 1.26611 1675 1.26607 1698 1.26603 1766 1.26598 1739 1.26594 1689 1.2659 1721 1.26586 1716 1.26582 1708 1.26578 C 1s/4 PNB700 2015 10 14 18 56 4 0 14 Casa Info Follows 1 Calib M = 280.725 A = 284.6 BE ADD 0 1 CASA region (*C 1s*) (*Shirley*) 1191.9937 1209.0952 0.278 2 0 0 299 542 275 9.3 (*C 1s*) 12.011 0 3 CASA comp (*C 1s*) (*GL(30)*) Area 317.6627 0.001 10000000 -1 1 MFWHM 1.2967439 0.3 7.5 -1 1 Position 1202.2266 1182.815 1212.815 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) CASA comp (*C 1s*) (*GL(30)*) Area 101.73293 0.001 10000000 -1 1 MFWHM 2.0895621 0.32335359 8.0838399 -1 1 Position 1200.956 1182.815 1212.815 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) CASA comp (*C 1s*) (*GL(30)*) Area 43.685583 0.001 10000000 -1 1 MFWHM 1.4619234 0.53336226 13.334057 -1 1 Position 1198.1714 1182.815 1212.815 -1 1 RSF 0.278 MASS 12.011 INDEX -1 (*C 1s*) CONST (**) pnb700.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 782 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 260 Charge Neutraliser :On Acquired On :15/10/14 18:56:04 XPS 79 1 3 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 C 1s -1 Kinetic Energy eV 1186.69 0.1 2 Intensity d Transmission d pulse counting 0.2597 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 602 684 1397 1.23374 1.24606 719 1.24606 788 1.24602 750 1.24598 717 1.24594 794 1.2459 774 1.24586 760 1.24581 748 1.24577 713 1.24573 741 1.24569 785 1.24565 784 1.24561 725 1.24557 799 1.24553 756 1.24549 684 1.24544 827 1.2454 799 1.24536 743 1.24532 776 1.24528 762 1.24524 773 1.2452 731 1.24516 748 1.24512 768 1.24507 712 1.24503 776 1.24499 769 1.24495 724 1.24491 788 1.24487 758 1.24483 762 1.24479 749 1.24475 748 1.24471 744 1.24466 716 1.24462 809 1.24458 771 1.24454 780 1.2445 806 1.24446 723 1.24442 781 1.24438 728 1.24434 741 1.24429 706 1.24425 742 1.24421 768 1.24417 747 1.24413 735 1.24409 743 1.24405 711 1.24401 700 1.24397 732 1.24392 741 1.24388 819 1.24384 728 1.2438 719 1.24376 773 1.24372 775 1.24368 720 1.24364 797 1.2436 723 1.24355 714 1.24351 753 1.24347 763 1.24343 781 1.24339 758 1.24335 787 1.24331 736 1.24327 702 1.24323 740 1.24319 756 1.24314 724 1.2431 788 1.24306 799 1.24302 753 1.24298 773 1.24294 771 1.2429 721 1.24286 732 1.24282 762 1.24277 726 1.24273 711 1.24269 744 1.24265 757 1.24261 737 1.24257 745 1.24253 738 1.24249 788 1.24245 737 1.2424 786 1.24236 751 1.24232 776 1.24228 746 1.24224 721 1.2422 767 1.24216 774 1.24212 762 1.24208 706 1.24203 714 1.24199 699 1.24195 729 1.24191 704 1.24187 725 1.24183 714 1.24179 766 1.24175 720 1.24171 696 1.24167 761 1.24162 772 1.24158 762 1.24154 752 1.2415 775 1.24146 745 1.24142 774 1.24138 742 1.24134 796 1.2413 738 1.24125 779 1.24121 748 1.24117 694 1.24113 746 1.24109 750 1.24105 797 1.24101 748 1.24097 734 1.24093 767 1.24088 736 1.24084 772 1.2408 775 1.24076 783 1.24072 754 1.24068 745 1.24064 759 1.2406 752 1.24056 726 1.24051 785 1.24047 751 1.24043 732 1.24039 735 1.24035 790 1.24031 784 1.24027 759 1.24023 777 1.24019 774 1.24015 807 1.2401 816 1.24006 811 1.24002 772 1.23998 799 1.23994 806 1.2399 834 1.23986 864 1.23982 850 1.23978 776 1.23973 835 1.23969 818 1.23965 809 1.23961 798 1.23957 926 1.23953 804 1.23949 762 1.23945 790 1.23941 778 1.23936 809 1.23932 783 1.23928 774 1.23924 823 1.2392 793 1.23916 816 1.23912 812 1.23908 838 1.23904 861 1.23899 817 1.23895 854 1.23891 806 1.23887 861 1.23883 894 1.23879 896 1.23875 856 1.23871 883 1.23867 939 1.23863 921 1.23858 977 1.23854 995 1.2385 1055 1.23846 1025 1.23842 1100 1.23838 1121 1.23834 1285 1.2383 1327 1.23826 1307 1.23821 1315 1.23817 1356 1.23813 1372 1.23809 1397 1.23805 1386 1.23801 1239 1.23797 1264 1.23793 1181 1.23789 1120 1.23784 1071 1.2378 952 1.23776 960 1.23772 876 1.23768 827 1.23764 811 1.2376 794 1.23756 815 1.23752 777 1.23747 762 1.23743 737 1.23739 788 1.23735 783 1.23731 777 1.23727 773 1.23723 735 1.23719 756 1.23715 702 1.23711 729 1.23706 739 1.23702 759 1.23698 778 1.23694 781 1.2369 735 1.23686 775 1.23682 737 1.23678 761 1.23674 761 1.23669 716 1.23665 758 1.23661 757 1.23657 763 1.23653 781 1.23649 723 1.23645 762 1.23641 819 1.23637 752 1.23632 726 1.23628 744 1.23624 740 1.2362 749 1.23616 769 1.23612 764 1.23608 769 1.23604 705 1.236 746 1.23595 717 1.23591 769 1.23587 716 1.23583 738 1.23579 710 1.23575 772 1.23571 755 1.23567 776 1.23563 731 1.23559 731 1.23554 733 1.2355 737 1.23546 759 1.23542 763 1.23538 764 1.23534 782 1.2353 736 1.23526 737 1.23522 787 1.23517 752 1.23513 727 1.23509 775 1.23505 742 1.23501 742 1.23497 787 1.23493 783 1.23489 757 1.23485 714 1.2348 773 1.23476 778 1.23472 739 1.23468 785 1.23464 737 1.2346 802 1.23456 764 1.23452 712 1.23448 753 1.23443 719 1.23439 753 1.23435 762 1.23431 768 1.23427 729 1.23423 780 1.23419 750 1.23415 761 1.23411 783 1.23407 773 1.23402 749 1.23398 734 1.23394 772 1.2339 800 1.23386 752 1.23382 802 1.23378 764 1.23374 Nb 3d/5 PNB700 2015 10 14 18 56 4 0 13 Casa Info Follows 1 Calib M = 280.725 A = 284.6 BE ADD 0 1 CASA region (*Nb 3d*) (*Shirley*) 1274.9084 1282.2562 2.921 2 0 0 299 542 275 9.3 (*Nb 3d*) 92.9064 0 2 CASA comp (*Nb 3d*) (*GL(30)*) Area 3329.5038 0.001 10000000 -1 1 MFWHM 1.0440134 0.24 6 -1 1 Position 1279.8233 1272.815 1285.815 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) CASA comp (*Nb 3d*) (*GL(30)*) Area 2211.7833 0.001 10000000 -1 1 MFWHM 1.0593033 0.24 6 -1 1 Position 1277.0766 1272.815 1285.815 -1 1 RSF 2.921 MASS 92.9064 INDEX -1 (*Nb 3d*) CONST (**) pnb700.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 1200 Sweeps: 20 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 458 Charge Neutraliser :On Acquired On :15/10/14 18:56:04 XPS 79 1 3 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Nb 3d -1 Kinetic Energy eV 1276.69 0.1 2 Intensity d Transmission d pulse counting 0.458 20 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 262 553 27836 1.20732 1.2118 1956 1.2118 1948 1.21177 1923 1.21173 1961 1.2117 1895 1.21166 1815 1.21163 1865 1.21159 1809 1.21156 1885 1.21152 1782 1.21149 1789 1.21146 1756 1.21142 1794 1.21139 1730 1.21135 1662 1.21132 1706 1.21128 1651 1.21125 1635 1.21121 1636 1.21118 1557 1.21115 1526 1.21111 1567 1.21108 1539 1.21104 1539 1.21101 1569 1.21097 1562 1.21094 1617 1.2109 1721 1.21087 1753 1.21084 1897 1.2108 2144 1.21077 2502 1.21073 3026 1.2107 3725 1.21066 4741 1.21063 6046 1.21059 7831 1.21056 9728 1.21053 11854 1.21049 14063 1.21046 16309 1.21042 17546 1.21039 18584 1.21035 18813 1.21032 18211 1.21029 16823 1.21025 14610 1.21022 12555 1.21018 9977 1.21015 7690 1.21011 5781 1.21008 4299 1.21004 3293 1.21001 2456 1.20998 1962 1.20994 1752 1.20991 1785 1.20987 1842 1.20984 2235 1.2098 2716 1.20977 3556 1.20973 4987 1.2097 6811 1.20967 9165 1.20963 11650 1.2096 15183 1.20956 18741 1.20953 21943 1.20949 24997 1.20946 27119 1.20942 27836 1.20939 26986 1.20936 25477 1.20932 22448 1.20929 18925 1.20925 15209 1.20922 11917 1.20918 8949 1.20915 6529 1.20911 4679 1.20908 3270 1.20905 2394 1.20901 1721 1.20898 1429 1.20894 1192 1.20891 967 1.20887 942 1.20884 850 1.2088 769 1.20877 740 1.20874 722 1.2087 704 1.20867 687 1.20863 721 1.2086 656 1.20856 657 1.20853 631 1.20849 646 1.20846 639 1.20843 643 1.20839 662 1.20836 600 1.20832 597 1.20829 628 1.20825 650 1.20822 589 1.20819 589 1.20815 611 1.20812 604 1.20808 640 1.20805 586 1.20801 593 1.20798 644 1.20794 588 1.20791 643 1.20788 620 1.20784 600 1.20781 646 1.20777 610 1.20774 646 1.2077 643 1.20767 575 1.20763 617 1.2076 599 1.20757 607 1.20753 574 1.2075 615 1.20746 553 1.20743 585 1.20739 609 1.20736 613 1.20732 Si 2p/6 PNB700 2015 10 14 18 56 4 0 10 Casa Info Follows 1 Calib M = 280.725 A = 284.6 BE ADD 0 0 0 pnb700.vms Dir:c:\users\tapiarem\desktop\phd\lab results\xps\xps data\niobium\ XPS Spectrum Lens Mode:Hybrid Resolution:Pass energy 40 Acqn. Time(s): 799 Sweeps: 10 Anode:Mono(Al (Mono))(156 W) Step(meV): 100.0 Dwell Time(ms): 397 Charge Neutraliser :On Acquired On :15/10/14 18:56:04 XPS 79 1 3 Mono(Al (Mono)) 1486.69 156 1e+037 1e+037 3000 3000 1e+037 1e+037 FAT 40 1e+037 -5.17 0 1e+037 1e+037 1e+037 1e+037 Si 2p -1 Kinetic Energy eV 1376.69 0.1 2 Intensity d Transmission d pulse counting 0.3974 10 0 1e+037 1e+037 1e+037 1 MFP Exponent d 0 402 246 398 1.19156 1.19218 277 1.19218 260 1.19218 301 1.19217 266 1.19217 294 1.19217 264 1.19216 268 1.19216 296 1.19216 286 1.19215 282 1.19215 312 1.19215 290 1.19214 291 1.19214 314 1.19214 271 1.19213 266 1.19213 287 1.19213 246 1.19213 261 1.19212 288 1.19212 288 1.19212 299 1.19211 313 1.19211 280 1.19211 274 1.1921 291 1.1921 310 1.1921 268 1.19209 305 1.19209 318 1.19209 288 1.19209 256 1.19208 305 1.19208 292 1.19208 313 1.19207 288 1.19207 307 1.19207 307 1.19206 306 1.19206 293 1.19206 303 1.19205 306 1.19205 305 1.19205 312 1.19205 298 1.19204 279 1.19204 318 1.19204 318 1.19203 264 1.19203 309 1.19203 298 1.19202 293 1.19202 308 1.19202 320 1.19201 274 1.19201 300 1.19201 315 1.19201 285 1.192 282 1.192 321 1.192 307 1.19199 279 1.19199 311 1.19199 311 1.19198 300 1.19198 313 1.19198 289 1.19197 277 1.19197 298 1.19197 302 1.19196 284 1.19196 292 1.19196 314 1.19196 292 1.19195 289 1.19195 268 1.19195 323 1.19194 309 1.19194 316 1.19194 298 1.19193 320 1.19193 306 1.19193 328 1.19192 333 1.19192 378 1.19192 306 1.19192 306 1.19191 307 1.19191 356 1.19191 312 1.1919 348 1.1919 326 1.1919 350 1.19189 339 1.19189 358 1.19189 358 1.19188 343 1.19188 343 1.19188 359 1.19188 357 1.19187 395 1.19187 398 1.19187 334 1.19186 341 1.19186 365 1.19186 366 1.19185 349 1.19185 339 1.19185 330 1.19184 314 1.19184 341 1.19184 337 1.19184 358 1.19183 288 1.19183 317 1.19183 254 1.19182 319 1.19182 298 1.19182 305 1.19181 334 1.19181 313 1.19181 280 1.1918 302 1.1918 309 1.1918 275 1.1918 282 1.19179 289 1.19179 279 1.19179 345 1.19178 302 1.19178 287 1.19178 331 1.19177 284 1.19177 306 1.19177 266 1.19176 289 1.19176 294 1.19176 286 1.19176 323 1.19175 274 1.19175 276 1.19175 295 1.19174 299 1.19174 296 1.19174 263 1.19173 277 1.19173 307 1.19173 303 1.19172 291 1.19172 331 1.19172 305 1.19171 326 1.19171 304 1.19171 284 1.19171 280 1.1917 321 1.1917 289 1.1917 304 1.19169 306 1.19169 294 1.19169 280 1.19168 265 1.19168 305 1.19168 316 1.19167 284 1.19167 272 1.19167 272 1.19167 317 1.19166 301 1.19166 292 1.19166 297 1.19165 302 1.19165 291 1.19165 293 1.19164 300 1.19164 317 1.19164 326 1.19163 311 1.19163 299 1.19163 295 1.19163 314 1.19162 314 1.19162 307 1.19162 305 1.19161 294 1.19161 289 1.19161 285 1.1916 291 1.1916 299 1.1916 314 1.19159 307 1.19159 307 1.19159 318 1.19159 316 1.19158 281 1.19158 287 1.19158 309 1.19157 308 1.19157 295 1.19157 261 1.19156 285 1.19156 end of experiment